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Crystal structure of N-(2-hydroxy-5-methylphenyl)benzamide
In the title compound, C(14)H(13)NO(2), the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C (r.m.s. deviation = 0.029 Å) forms dihedral angles of 5.63 (6) and 10.20 (5)° with the phenyl and hydroxyphenyl rings, respectively. A short intramolecular N—H⋯O contact is present....
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719913/ https://www.ncbi.nlm.nih.gov/pubmed/26870541 http://dx.doi.org/10.1107/S2056989015020575 |
Sumario: | In the title compound, C(14)H(13)NO(2), the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C (r.m.s. deviation = 0.029 Å) forms dihedral angles of 5.63 (6) and 10.20 (5)° with the phenyl and hydroxyphenyl rings, respectively. A short intramolecular N—H⋯O contact is present. In the crystal, the molecules are linked by O—H⋯O hydrogen bonds to generate C(7) chains along [100]. The chains are reinforced by weak C—H⋯O contacts, which together with the O—H⋯O bonds lead to R (2) (2)(7) loops. Very weak N—H⋯O interactions link the molecules into inversion dimers. |
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