Crystal structure of N-(2-hy­droxy-5-methyl­phen­yl)benzamide

In the title compound, C(14)H(13)NO(2), the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C (r.m.s. deviation = 0.029 Å) forms dihedral angles of 5.63 (6) and 10.20 (5)° with the phenyl and hy­droxy­phenyl rings, respectively. A short intra­molecular N—H⋯O contact is present....

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Autores principales: Moreno-Fuquen, Rodolfo, Mariño, Nory J., Kennedy, Alan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719913/
https://www.ncbi.nlm.nih.gov/pubmed/26870541
http://dx.doi.org/10.1107/S2056989015020575
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author Moreno-Fuquen, Rodolfo
Mariño, Nory J.
Kennedy, Alan R.
author_facet Moreno-Fuquen, Rodolfo
Mariño, Nory J.
Kennedy, Alan R.
author_sort Moreno-Fuquen, Rodolfo
collection PubMed
description In the title compound, C(14)H(13)NO(2), the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C (r.m.s. deviation = 0.029 Å) forms dihedral angles of 5.63 (6) and 10.20 (5)° with the phenyl and hy­droxy­phenyl rings, respectively. A short intra­molecular N—H⋯O contact is present. In the crystal, the mol­ecules are linked by O—H⋯O hydrogen bonds to generate C(7) chains along [100]. The chains are reinforced by weak C—H⋯O contacts, which together with the O—H⋯O bonds lead to R (2) (2)(7) loops. Very weak N—H⋯O inter­actions link the mol­ecules into inversion dimers.
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spelling pubmed-47199132016-02-11 Crystal structure of N-(2-hy­droxy-5-methyl­phen­yl)benzamide Moreno-Fuquen, Rodolfo Mariño, Nory J. Kennedy, Alan R. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(14)H(13)NO(2), the mean plane of the non-H atoms of the central amide fragment C—N—C(=O)—C (r.m.s. deviation = 0.029 Å) forms dihedral angles of 5.63 (6) and 10.20 (5)° with the phenyl and hy­droxy­phenyl rings, respectively. A short intra­molecular N—H⋯O contact is present. In the crystal, the mol­ecules are linked by O—H⋯O hydrogen bonds to generate C(7) chains along [100]. The chains are reinforced by weak C—H⋯O contacts, which together with the O—H⋯O bonds lead to R (2) (2)(7) loops. Very weak N—H⋯O inter­actions link the mol­ecules into inversion dimers. International Union of Crystallography 2015-11-14 /pmc/articles/PMC4719913/ /pubmed/26870541 http://dx.doi.org/10.1107/S2056989015020575 Text en © Moreno-Fuquen et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Moreno-Fuquen, Rodolfo
Mariño, Nory J.
Kennedy, Alan R.
Crystal structure of N-(2-hy­droxy-5-methyl­phen­yl)benzamide
title Crystal structure of N-(2-hy­droxy-5-methyl­phen­yl)benzamide
title_full Crystal structure of N-(2-hy­droxy-5-methyl­phen­yl)benzamide
title_fullStr Crystal structure of N-(2-hy­droxy-5-methyl­phen­yl)benzamide
title_full_unstemmed Crystal structure of N-(2-hy­droxy-5-methyl­phen­yl)benzamide
title_short Crystal structure of N-(2-hy­droxy-5-methyl­phen­yl)benzamide
title_sort crystal structure of n-(2-hy­droxy-5-methyl­phen­yl)benzamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719913/
https://www.ncbi.nlm.nih.gov/pubmed/26870541
http://dx.doi.org/10.1107/S2056989015020575
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