Crystal structure of 1-[(2,2-dimethyl-1,3-dioxolan-4-yl)meth­yl]-2-(thia­zol-4-yl)-1H-benzimidazole

The benzimidazole ring in the title compound, C(16)H(17)N(3)O(2)S, is almost planar, with the greatest deviation from the mean plane being 0.032 (1) Å. The fused-ring system makes dihedral angles of 19.91 (7) and 24.51 (8)° with the best plane through each of the thia­zol-4-yl and 1,3-dioxolan-4-yl...

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Autores principales: Gueddar, Hicham, Bouhfid, Rachid, Essassi, El Mokhtar, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719918/
https://www.ncbi.nlm.nih.gov/pubmed/26870546
http://dx.doi.org/10.1107/S205698901502085X
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author Gueddar, Hicham
Bouhfid, Rachid
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
author_facet Gueddar, Hicham
Bouhfid, Rachid
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
author_sort Gueddar, Hicham
collection PubMed
description The benzimidazole ring in the title compound, C(16)H(17)N(3)O(2)S, is almost planar, with the greatest deviation from the mean plane being 0.032 (1) Å. The fused-ring system makes dihedral angles of 19.91 (7) and 24.51 (8)° with the best plane through each of the thia­zol-4-yl and 1,3-dioxolan-4-yl rings, respectively; the latter exhibits an envelope conformation with the methyl­ene C atom being the flap. Finally, the thia­zol-4-yl ring makes a dihedral angle of 33.85 (9)° with the 1,3-dioxolan-4-yl ring. In the crystal, mol­ecules are connected by a pair of C—H⋯π(imidazole) inter­actions to form centrosymmetric aggregates.
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spelling pubmed-47199182016-02-11 Crystal structure of 1-[(2,2-dimethyl-1,3-dioxolan-4-yl)meth­yl]-2-(thia­zol-4-yl)-1H-benzimidazole Gueddar, Hicham Bouhfid, Rachid Essassi, El Mokhtar Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr E Crystallogr Commun Data Reports The benzimidazole ring in the title compound, C(16)H(17)N(3)O(2)S, is almost planar, with the greatest deviation from the mean plane being 0.032 (1) Å. The fused-ring system makes dihedral angles of 19.91 (7) and 24.51 (8)° with the best plane through each of the thia­zol-4-yl and 1,3-dioxolan-4-yl rings, respectively; the latter exhibits an envelope conformation with the methyl­ene C atom being the flap. Finally, the thia­zol-4-yl ring makes a dihedral angle of 33.85 (9)° with the 1,3-dioxolan-4-yl ring. In the crystal, mol­ecules are connected by a pair of C—H⋯π(imidazole) inter­actions to form centrosymmetric aggregates. International Union of Crystallography 2015-11-18 /pmc/articles/PMC4719918/ /pubmed/26870546 http://dx.doi.org/10.1107/S205698901502085X Text en © Gueddar et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Gueddar, Hicham
Bouhfid, Rachid
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
Crystal structure of 1-[(2,2-dimethyl-1,3-dioxolan-4-yl)meth­yl]-2-(thia­zol-4-yl)-1H-benzimidazole
title Crystal structure of 1-[(2,2-dimethyl-1,3-dioxolan-4-yl)meth­yl]-2-(thia­zol-4-yl)-1H-benzimidazole
title_full Crystal structure of 1-[(2,2-dimethyl-1,3-dioxolan-4-yl)meth­yl]-2-(thia­zol-4-yl)-1H-benzimidazole
title_fullStr Crystal structure of 1-[(2,2-dimethyl-1,3-dioxolan-4-yl)meth­yl]-2-(thia­zol-4-yl)-1H-benzimidazole
title_full_unstemmed Crystal structure of 1-[(2,2-dimethyl-1,3-dioxolan-4-yl)meth­yl]-2-(thia­zol-4-yl)-1H-benzimidazole
title_short Crystal structure of 1-[(2,2-dimethyl-1,3-dioxolan-4-yl)meth­yl]-2-(thia­zol-4-yl)-1H-benzimidazole
title_sort crystal structure of 1-[(2,2-dimethyl-1,3-dioxolan-4-yl)meth­yl]-2-(thia­zol-4-yl)-1h-benzimidazole
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719918/
https://www.ncbi.nlm.nih.gov/pubmed/26870546
http://dx.doi.org/10.1107/S205698901502085X
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