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Crystal structure of 2-(2,3-dimethylanilino)-N′-[(1E)-2-hydroxybenzylidene]benzohydrazide
The asymmetric unit of the title compound, C(22)H(21)N(3)O(2), consists of two independent molecules (A and B) having differing conformations. The differences mainly concern the dihedral angles which the hydroxyphenyl and dimethylphenyl rings subtend to the central phenylene ring, these being...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719921/ https://www.ncbi.nlm.nih.gov/pubmed/26870549 http://dx.doi.org/10.1107/S2056989015021532 |
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author | Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Mohamed, Alaa F. Albayati, Mustafa R. |
author_facet | Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Mohamed, Alaa F. Albayati, Mustafa R. |
author_sort | Mohamed, Shaaban K. |
collection | PubMed |
description | The asymmetric unit of the title compound, C(22)H(21)N(3)O(2), consists of two independent molecules (A and B) having differing conformations. The differences mainly concern the dihedral angles which the hydroxyphenyl and dimethylphenyl rings subtend to the central phenylene ring, these being 30.16 (6) and 58.60 (6)° in molecule A and 13.42 (7) and 60.31 (7)° in B. With the exception of the dimethyphenyl substituent, the conformations of the rest of each molecule are largely determined by intramolecular O—H⋯N and N—H⋯O hydrogen bonds. In the crystal, N—H⋯O hydrogen bonds link the molecules into chains extending parallel to the a axis in which the types of molecules alternate in an …A…B…A…B… fashion. |
format | Online Article Text |
id | pubmed-4719921 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-47199212016-02-11 Crystal structure of 2-(2,3-dimethylanilino)-N′-[(1E)-2-hydroxybenzylidene]benzohydrazide Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Mohamed, Alaa F. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, C(22)H(21)N(3)O(2), consists of two independent molecules (A and B) having differing conformations. The differences mainly concern the dihedral angles which the hydroxyphenyl and dimethylphenyl rings subtend to the central phenylene ring, these being 30.16 (6) and 58.60 (6)° in molecule A and 13.42 (7) and 60.31 (7)° in B. With the exception of the dimethyphenyl substituent, the conformations of the rest of each molecule are largely determined by intramolecular O—H⋯N and N—H⋯O hydrogen bonds. In the crystal, N—H⋯O hydrogen bonds link the molecules into chains extending parallel to the a axis in which the types of molecules alternate in an …A…B…A…B… fashion. International Union of Crystallography 2015-11-21 /pmc/articles/PMC4719921/ /pubmed/26870549 http://dx.doi.org/10.1107/S2056989015021532 Text en © Mohamed et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Mohamed, Alaa F. Albayati, Mustafa R. Crystal structure of 2-(2,3-dimethylanilino)-N′-[(1E)-2-hydroxybenzylidene]benzohydrazide |
title | Crystal structure of 2-(2,3-dimethylanilino)-N′-[(1E)-2-hydroxybenzylidene]benzohydrazide |
title_full | Crystal structure of 2-(2,3-dimethylanilino)-N′-[(1E)-2-hydroxybenzylidene]benzohydrazide |
title_fullStr | Crystal structure of 2-(2,3-dimethylanilino)-N′-[(1E)-2-hydroxybenzylidene]benzohydrazide |
title_full_unstemmed | Crystal structure of 2-(2,3-dimethylanilino)-N′-[(1E)-2-hydroxybenzylidene]benzohydrazide |
title_short | Crystal structure of 2-(2,3-dimethylanilino)-N′-[(1E)-2-hydroxybenzylidene]benzohydrazide |
title_sort | crystal structure of 2-(2,3-dimethylanilino)-n′-[(1e)-2-hydroxybenzylidene]benzohydrazide |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719921/ https://www.ncbi.nlm.nih.gov/pubmed/26870549 http://dx.doi.org/10.1107/S2056989015021532 |
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