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Crystal structure of 2-(2,3-di­methyl­anilino)-N′-[(1E)-2-hy­droxy­benzyl­idene]benzohydrazide

The asymmetric unit of the title compound, C(22)H(21)N(3)O(2), consists of two independent mol­ecules (A and B) having differing conformations. The differences mainly concern the dihedral angles which the hy­droxy­phenyl and di­methyl­phenyl rings subtend to the central phenyl­ene ring, these being...

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Autores principales: Mohamed, Shaaban K., Mague, Joel T., Akkurt, Mehmet, Mohamed, Alaa F., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719921/
https://www.ncbi.nlm.nih.gov/pubmed/26870549
http://dx.doi.org/10.1107/S2056989015021532
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author Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Mohamed, Alaa F.
Albayati, Mustafa R.
author_facet Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Mohamed, Alaa F.
Albayati, Mustafa R.
author_sort Mohamed, Shaaban K.
collection PubMed
description The asymmetric unit of the title compound, C(22)H(21)N(3)O(2), consists of two independent mol­ecules (A and B) having differing conformations. The differences mainly concern the dihedral angles which the hy­droxy­phenyl and di­methyl­phenyl rings subtend to the central phenyl­ene ring, these being 30.16 (6) and 58.60 (6)° in mol­ecule A and 13.42 (7) and 60.31 (7)° in B. With the exception of the dimethyphenyl substituent, the conformations of the rest of each mol­ecule are largely determined by intra­molecular O—H⋯N and N—H⋯O hydrogen bonds. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into chains extending parallel to the a axis in which the types of mol­ecules alternate in an …A…B…A…B… fashion.
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spelling pubmed-47199212016-02-11 Crystal structure of 2-(2,3-di­methyl­anilino)-N′-[(1E)-2-hy­droxy­benzyl­idene]benzohydrazide Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Mohamed, Alaa F. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, C(22)H(21)N(3)O(2), consists of two independent mol­ecules (A and B) having differing conformations. The differences mainly concern the dihedral angles which the hy­droxy­phenyl and di­methyl­phenyl rings subtend to the central phenyl­ene ring, these being 30.16 (6) and 58.60 (6)° in mol­ecule A and 13.42 (7) and 60.31 (7)° in B. With the exception of the dimethyphenyl substituent, the conformations of the rest of each mol­ecule are largely determined by intra­molecular O—H⋯N and N—H⋯O hydrogen bonds. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into chains extending parallel to the a axis in which the types of mol­ecules alternate in an …A…B…A…B… fashion. International Union of Crystallography 2015-11-21 /pmc/articles/PMC4719921/ /pubmed/26870549 http://dx.doi.org/10.1107/S2056989015021532 Text en © Mohamed et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Mohamed, Alaa F.
Albayati, Mustafa R.
Crystal structure of 2-(2,3-di­methyl­anilino)-N′-[(1E)-2-hy­droxy­benzyl­idene]benzohydrazide
title Crystal structure of 2-(2,3-di­methyl­anilino)-N′-[(1E)-2-hy­droxy­benzyl­idene]benzohydrazide
title_full Crystal structure of 2-(2,3-di­methyl­anilino)-N′-[(1E)-2-hy­droxy­benzyl­idene]benzohydrazide
title_fullStr Crystal structure of 2-(2,3-di­methyl­anilino)-N′-[(1E)-2-hy­droxy­benzyl­idene]benzohydrazide
title_full_unstemmed Crystal structure of 2-(2,3-di­methyl­anilino)-N′-[(1E)-2-hy­droxy­benzyl­idene]benzohydrazide
title_short Crystal structure of 2-(2,3-di­methyl­anilino)-N′-[(1E)-2-hy­droxy­benzyl­idene]benzohydrazide
title_sort crystal structure of 2-(2,3-di­methyl­anilino)-n′-[(1e)-2-hy­droxy­benzyl­idene]benzohydrazide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719921/
https://www.ncbi.nlm.nih.gov/pubmed/26870549
http://dx.doi.org/10.1107/S2056989015021532
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