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Crystal structure of 5,5′-bis­(di­methyl­amino)-N,N′-(3-methyl-3-aza­pentane-1,5-di­yl)di(naphthalene-1-sulfonamide)

In the title compound, C(29)H(37)N(5)O(4)S(2), two arms substituted with dansyl derivatives are connected to a central tertiary amine, where the dihedral angle between the planes of two dansyl units is 56.39 (4)°. Each arm contains a sulfonamide functional group and both N—H groups in the compound a...

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Autores principales: Horne, Toyketa V., Haque, Syed A., Barton, Adrianne, Hossain, Md. Alamgir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719922/
https://www.ncbi.nlm.nih.gov/pubmed/26870550
http://dx.doi.org/10.1107/S2056989015021714
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author Horne, Toyketa V.
Haque, Syed A.
Barton, Adrianne
Hossain, Md. Alamgir
author_facet Horne, Toyketa V.
Haque, Syed A.
Barton, Adrianne
Hossain, Md. Alamgir
author_sort Horne, Toyketa V.
collection PubMed
description In the title compound, C(29)H(37)N(5)O(4)S(2), two arms substituted with dansyl derivatives are connected to a central tertiary amine, where the dihedral angle between the planes of two dansyl units is 56.39 (4)°. Each arm contains a sulfonamide functional group and both N—H groups in the compound are pointed to the same side. The central part of the mol­ecule is disordered over three sets of sites with a refined occupancy ratio of 0.547 (4):0.328 (4):0.125 (3). No intra­molecular π–π or hydrogen-bonding inter­actions are observed. In the crystal, mol­ecules are linked via pairs of N—H⋯O inter­actions involving the same acceptor atom, forming inversion dimers. In addition, C—H⋯O inter­actions exist between molecules, providing further stabilization of dimers.
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spelling pubmed-47199222016-02-11 Crystal structure of 5,5′-bis­(di­methyl­amino)-N,N′-(3-methyl-3-aza­pentane-1,5-di­yl)di(naphthalene-1-sulfonamide) Horne, Toyketa V. Haque, Syed A. Barton, Adrianne Hossain, Md. Alamgir Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(29)H(37)N(5)O(4)S(2), two arms substituted with dansyl derivatives are connected to a central tertiary amine, where the dihedral angle between the planes of two dansyl units is 56.39 (4)°. Each arm contains a sulfonamide functional group and both N—H groups in the compound are pointed to the same side. The central part of the mol­ecule is disordered over three sets of sites with a refined occupancy ratio of 0.547 (4):0.328 (4):0.125 (3). No intra­molecular π–π or hydrogen-bonding inter­actions are observed. In the crystal, mol­ecules are linked via pairs of N—H⋯O inter­actions involving the same acceptor atom, forming inversion dimers. In addition, C—H⋯O inter­actions exist between molecules, providing further stabilization of dimers. International Union of Crystallography 2015-11-21 /pmc/articles/PMC4719922/ /pubmed/26870550 http://dx.doi.org/10.1107/S2056989015021714 Text en © Horne et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Horne, Toyketa V.
Haque, Syed A.
Barton, Adrianne
Hossain, Md. Alamgir
Crystal structure of 5,5′-bis­(di­methyl­amino)-N,N′-(3-methyl-3-aza­pentane-1,5-di­yl)di(naphthalene-1-sulfonamide)
title Crystal structure of 5,5′-bis­(di­methyl­amino)-N,N′-(3-methyl-3-aza­pentane-1,5-di­yl)di(naphthalene-1-sulfonamide)
title_full Crystal structure of 5,5′-bis­(di­methyl­amino)-N,N′-(3-methyl-3-aza­pentane-1,5-di­yl)di(naphthalene-1-sulfonamide)
title_fullStr Crystal structure of 5,5′-bis­(di­methyl­amino)-N,N′-(3-methyl-3-aza­pentane-1,5-di­yl)di(naphthalene-1-sulfonamide)
title_full_unstemmed Crystal structure of 5,5′-bis­(di­methyl­amino)-N,N′-(3-methyl-3-aza­pentane-1,5-di­yl)di(naphthalene-1-sulfonamide)
title_short Crystal structure of 5,5′-bis­(di­methyl­amino)-N,N′-(3-methyl-3-aza­pentane-1,5-di­yl)di(naphthalene-1-sulfonamide)
title_sort crystal structure of 5,5′-bis­(di­methyl­amino)-n,n′-(3-methyl-3-aza­pentane-1,5-di­yl)di(naphthalene-1-sulfonamide)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719922/
https://www.ncbi.nlm.nih.gov/pubmed/26870550
http://dx.doi.org/10.1107/S2056989015021714
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