Crystal structure of N′-[bis­(ethyl­sulfan­yl)methyl­idene]-2-hy­droxy-4-meth­oxy­benzohydrazide

In the title compound, C(13)H(18)N(2)O(3)S(2), the amide group is in the plane of the ­benzoyl ring with a C—N—N—C torsion angle of 177.63 (12)°. The two di­thio­ate groups are in an anti conformation [torsion angles = 173.68 (8) and −9.98 (10)°]. An intra­molecular N—H⋯O hydrogen bond is observed....

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Autores principales: Nath, Paras, Bharty, Manoj K., Chaurasia, Rahul, Kumari, Sanyucta, Gupta, Sushil K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719926/
https://www.ncbi.nlm.nih.gov/pubmed/26870554
http://dx.doi.org/10.1107/S2056989015021271
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author Nath, Paras
Bharty, Manoj K.
Chaurasia, Rahul
Kumari, Sanyucta
Gupta, Sushil K.
author_facet Nath, Paras
Bharty, Manoj K.
Chaurasia, Rahul
Kumari, Sanyucta
Gupta, Sushil K.
author_sort Nath, Paras
collection PubMed
description In the title compound, C(13)H(18)N(2)O(3)S(2), the amide group is in the plane of the ­benzoyl ring with a C—N—N—C torsion angle of 177.63 (12)°. The two di­thio­ate groups are in an anti conformation [torsion angles = 173.68 (8) and −9.98 (10)°]. An intra­molecular N—H⋯O hydrogen bond is observed. In the crystal, an O—H⋯O hydrogen bond and a weak C—H⋯O contact involving the same acceptor atom generate an S(6) ring motif and give rise to chains along [010].
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spelling pubmed-47199262016-02-11 Crystal structure of N′-[bis­(ethyl­sulfan­yl)methyl­idene]-2-hy­droxy-4-meth­oxy­benzohydrazide Nath, Paras Bharty, Manoj K. Chaurasia, Rahul Kumari, Sanyucta Gupta, Sushil K. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(13)H(18)N(2)O(3)S(2), the amide group is in the plane of the ­benzoyl ring with a C—N—N—C torsion angle of 177.63 (12)°. The two di­thio­ate groups are in an anti conformation [torsion angles = 173.68 (8) and −9.98 (10)°]. An intra­molecular N—H⋯O hydrogen bond is observed. In the crystal, an O—H⋯O hydrogen bond and a weak C—H⋯O contact involving the same acceptor atom generate an S(6) ring motif and give rise to chains along [010]. International Union of Crystallography 2015-11-21 /pmc/articles/PMC4719926/ /pubmed/26870554 http://dx.doi.org/10.1107/S2056989015021271 Text en © Nath et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Nath, Paras
Bharty, Manoj K.
Chaurasia, Rahul
Kumari, Sanyucta
Gupta, Sushil K.
Crystal structure of N′-[bis­(ethyl­sulfan­yl)methyl­idene]-2-hy­droxy-4-meth­oxy­benzohydrazide
title Crystal structure of N′-[bis­(ethyl­sulfan­yl)methyl­idene]-2-hy­droxy-4-meth­oxy­benzohydrazide
title_full Crystal structure of N′-[bis­(ethyl­sulfan­yl)methyl­idene]-2-hy­droxy-4-meth­oxy­benzohydrazide
title_fullStr Crystal structure of N′-[bis­(ethyl­sulfan­yl)methyl­idene]-2-hy­droxy-4-meth­oxy­benzohydrazide
title_full_unstemmed Crystal structure of N′-[bis­(ethyl­sulfan­yl)methyl­idene]-2-hy­droxy-4-meth­oxy­benzohydrazide
title_short Crystal structure of N′-[bis­(ethyl­sulfan­yl)methyl­idene]-2-hy­droxy-4-meth­oxy­benzohydrazide
title_sort crystal structure of n′-[bis­(ethyl­sulfan­yl)methyl­idene]-2-hy­droxy-4-meth­oxy­benzohydrazide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719926/
https://www.ncbi.nlm.nih.gov/pubmed/26870554
http://dx.doi.org/10.1107/S2056989015021271
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