Crystal structure of phenyl N-(4-nitro­phen­yl)carbamate

The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two independent mol­ecules (A and B). The dihedral angle between the aromatic rings is 48.18 (14)° in mol­ecule A and 45.81 (14)° in mol­ecule B. The mean plane of the carbamate N—C(=O)—O group is twisted slightly from the attac...

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Detalles Bibliográficos
Autores principales: AaminaNaaz, Y., Sathiyaraj, Subramaniyan, Kalaimani, Sundararaj, Nasar, A. Sultan, SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719927/
https://www.ncbi.nlm.nih.gov/pubmed/26870555
http://dx.doi.org/10.1107/S2056989015021544
Descripción
Sumario:The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two independent mol­ecules (A and B). The dihedral angle between the aromatic rings is 48.18 (14)° in mol­ecule A and 45.81 (14)° in mol­ecule B. The mean plane of the carbamate N—C(=O)—O group is twisted slightly from the attached benzene and phenyl rings, making respective dihedral angles of 12.97 (13) and 60.93 (14)° in A, and 23.11 (14) and 59.10 (14)° in B. In the crystal, A and B mol­ecules are arranged alternately through N—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming chains along the a axis. The chains are further linked by C—H⋯O hydrogen bonds into a double-chain structure.

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