Crystal structure of phenyl N-(4-nitro­phen­yl)carbamate

The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two independent mol­ecules (A and B). The dihedral angle between the aromatic rings is 48.18 (14)° in mol­ecule A and 45.81 (14)° in mol­ecule B. The mean plane of the carbamate N—C(=O)—O group is twisted slightly from the attac...

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Autores principales: AaminaNaaz, Y., Sathiyaraj, Subramaniyan, Kalaimani, Sundararaj, Nasar, A. Sultan, SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719927/
https://www.ncbi.nlm.nih.gov/pubmed/26870555
http://dx.doi.org/10.1107/S2056989015021544
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author AaminaNaaz, Y.
Sathiyaraj, Subramaniyan
Kalaimani, Sundararaj
Nasar, A. Sultan
SubbiahPandi, A.
author_facet AaminaNaaz, Y.
Sathiyaraj, Subramaniyan
Kalaimani, Sundararaj
Nasar, A. Sultan
SubbiahPandi, A.
author_sort AaminaNaaz, Y.
collection PubMed
description The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two independent mol­ecules (A and B). The dihedral angle between the aromatic rings is 48.18 (14)° in mol­ecule A and 45.81 (14)° in mol­ecule B. The mean plane of the carbamate N—C(=O)—O group is twisted slightly from the attached benzene and phenyl rings, making respective dihedral angles of 12.97 (13) and 60.93 (14)° in A, and 23.11 (14) and 59.10 (14)° in B. In the crystal, A and B mol­ecules are arranged alternately through N—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming chains along the a axis. The chains are further linked by C—H⋯O hydrogen bonds into a double-chain structure.
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spelling pubmed-47199272016-02-11 Crystal structure of phenyl N-(4-nitro­phen­yl)carbamate AaminaNaaz, Y. Sathiyaraj, Subramaniyan Kalaimani, Sundararaj Nasar, A. Sultan SubbiahPandi, A. Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two independent mol­ecules (A and B). The dihedral angle between the aromatic rings is 48.18 (14)° in mol­ecule A and 45.81 (14)° in mol­ecule B. The mean plane of the carbamate N—C(=O)—O group is twisted slightly from the attached benzene and phenyl rings, making respective dihedral angles of 12.97 (13) and 60.93 (14)° in A, and 23.11 (14) and 59.10 (14)° in B. In the crystal, A and B mol­ecules are arranged alternately through N—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming chains along the a axis. The chains are further linked by C—H⋯O hydrogen bonds into a double-chain structure. International Union of Crystallography 2015-11-21 /pmc/articles/PMC4719927/ /pubmed/26870555 http://dx.doi.org/10.1107/S2056989015021544 Text en © AaminaNaaz et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
AaminaNaaz, Y.
Sathiyaraj, Subramaniyan
Kalaimani, Sundararaj
Nasar, A. Sultan
SubbiahPandi, A.
Crystal structure of phenyl N-(4-nitro­phen­yl)carbamate
title Crystal structure of phenyl N-(4-nitro­phen­yl)carbamate
title_full Crystal structure of phenyl N-(4-nitro­phen­yl)carbamate
title_fullStr Crystal structure of phenyl N-(4-nitro­phen­yl)carbamate
title_full_unstemmed Crystal structure of phenyl N-(4-nitro­phen­yl)carbamate
title_short Crystal structure of phenyl N-(4-nitro­phen­yl)carbamate
title_sort crystal structure of phenyl n-(4-nitro­phen­yl)carbamate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719927/
https://www.ncbi.nlm.nih.gov/pubmed/26870555
http://dx.doi.org/10.1107/S2056989015021544
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