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Crystal structure of 3-benzyl-1-[(1,2,3,4-tetrahydronaphthalen-1-ylidene)amino]thiourea
In the title compound, C(18)H(19)N(3)S, the dihedral angle between the planes of the benzene rings is 58.63 (8)°. The six-membered ring bonded to the thiosemicarbazide group (r.m.s. deviation = 0.038 Å) adopts a sofa conformation, with one of the methylene-group C atoms as the flap. A short intra...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719930/ https://www.ncbi.nlm.nih.gov/pubmed/26870558 http://dx.doi.org/10.1107/S2056989015021064 |
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| author | Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Hassan, Alaa A Abdel-Aziz, Ahmed T. Albayati, Mustafa R. |
| author_facet | Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Hassan, Alaa A Abdel-Aziz, Ahmed T. Albayati, Mustafa R. |
| author_sort | Mohamed, Shaaban K. |
| collection | PubMed |
| description | In the title compound, C(18)H(19)N(3)S, the dihedral angle between the planes of the benzene rings is 58.63 (8)°. The six-membered ring bonded to the thiosemicarbazide group (r.m.s. deviation = 0.038 Å) adopts a sofa conformation, with one of the methylene-group C atoms as the flap. A short intramolecular N—H⋯N contact is observed. In the crystal, molecules are linked by weak N—H⋯S interactions to generate C(4) chains propagating in the [010] direction, with adjacent molecules related by glide symmetry. |
| format | Online Article Text |
| id | pubmed-4719930 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-47199302016-02-11 Crystal structure of 3-benzyl-1-[(1,2,3,4-tetrahydronaphthalen-1-ylidene)amino]thiourea Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Hassan, Alaa A Abdel-Aziz, Ahmed T. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(18)H(19)N(3)S, the dihedral angle between the planes of the benzene rings is 58.63 (8)°. The six-membered ring bonded to the thiosemicarbazide group (r.m.s. deviation = 0.038 Å) adopts a sofa conformation, with one of the methylene-group C atoms as the flap. A short intramolecular N—H⋯N contact is observed. In the crystal, molecules are linked by weak N—H⋯S interactions to generate C(4) chains propagating in the [010] direction, with adjacent molecules related by glide symmetry. International Union of Crystallography 2015-11-21 /pmc/articles/PMC4719930/ /pubmed/26870558 http://dx.doi.org/10.1107/S2056989015021064 Text en © Mohamed et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Hassan, Alaa A Abdel-Aziz, Ahmed T. Albayati, Mustafa R. Crystal structure of 3-benzyl-1-[(1,2,3,4-tetrahydronaphthalen-1-ylidene)amino]thiourea |
| title | Crystal structure of 3-benzyl-1-[(1,2,3,4-tetrahydronaphthalen-1-ylidene)amino]thiourea |
| title_full | Crystal structure of 3-benzyl-1-[(1,2,3,4-tetrahydronaphthalen-1-ylidene)amino]thiourea |
| title_fullStr | Crystal structure of 3-benzyl-1-[(1,2,3,4-tetrahydronaphthalen-1-ylidene)amino]thiourea |
| title_full_unstemmed | Crystal structure of 3-benzyl-1-[(1,2,3,4-tetrahydronaphthalen-1-ylidene)amino]thiourea |
| title_short | Crystal structure of 3-benzyl-1-[(1,2,3,4-tetrahydronaphthalen-1-ylidene)amino]thiourea |
| title_sort | crystal structure of 3-benzyl-1-[(1,2,3,4-tetrahydronaphthalen-1-ylidene)amino]thiourea |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719930/ https://www.ncbi.nlm.nih.gov/pubmed/26870558 http://dx.doi.org/10.1107/S2056989015021064 |
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