Crystal structure of 2-butyl­sulfanyl-4,6-bis­[(E)-4-(di­methyl­amino)­styr­yl]pyrimidine

In the title compound, C(28)H(34)N(4)S, the dihedral angles between the pyrimidine ring and the pendant 4-(di­methyl­amino)­benzene rings are 14.20 (5) and 14.56 (4)°. The butyl side chain adopts an anti conformation [C—C—C—C = −171.53 (13)°]. No directional inter­actions beyond van der Waals contac...

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Detalles Bibliográficos
Autores principales: Song, Jingbao, Zhou, Qiang, Wang, Aijian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719932/
https://www.ncbi.nlm.nih.gov/pubmed/26870560
http://dx.doi.org/10.1107/S2056989015021441
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author Song, Jingbao
Zhou, Qiang
Wang, Aijian
author_facet Song, Jingbao
Zhou, Qiang
Wang, Aijian
author_sort Song, Jingbao
collection PubMed
description In the title compound, C(28)H(34)N(4)S, the dihedral angles between the pyrimidine ring and the pendant 4-(di­methyl­amino)­benzene rings are 14.20 (5) and 14.56 (4)°. The butyl side chain adopts an anti conformation [C—C—C—C = −171.53 (13)°]. No directional inter­actions beyond van der Waals contacts occur in the crystal structure The title mol­ecule has a D–A–D structure, in which the pyrimidine ring is the electron-withdrawing part and the 4-(di­methyl­amino)­benzene rings are the electron-donating parts.
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spelling pubmed-47199322016-02-11 Crystal structure of 2-butyl­sulfanyl-4,6-bis­[(E)-4-(di­methyl­amino)­styr­yl]pyrimidine Song, Jingbao Zhou, Qiang Wang, Aijian Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(28)H(34)N(4)S, the dihedral angles between the pyrimidine ring and the pendant 4-(di­methyl­amino)­benzene rings are 14.20 (5) and 14.56 (4)°. The butyl side chain adopts an anti conformation [C—C—C—C = −171.53 (13)°]. No directional inter­actions beyond van der Waals contacts occur in the crystal structure The title mol­ecule has a D–A–D structure, in which the pyrimidine ring is the electron-withdrawing part and the 4-(di­methyl­amino)­benzene rings are the electron-donating parts. International Union of Crystallography 2015-11-21 /pmc/articles/PMC4719932/ /pubmed/26870560 http://dx.doi.org/10.1107/S2056989015021441 Text en © Song et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Song, Jingbao
Zhou, Qiang
Wang, Aijian
Crystal structure of 2-butyl­sulfanyl-4,6-bis­[(E)-4-(di­methyl­amino)­styr­yl]pyrimidine
title Crystal structure of 2-butyl­sulfanyl-4,6-bis­[(E)-4-(di­methyl­amino)­styr­yl]pyrimidine
title_full Crystal structure of 2-butyl­sulfanyl-4,6-bis­[(E)-4-(di­methyl­amino)­styr­yl]pyrimidine
title_fullStr Crystal structure of 2-butyl­sulfanyl-4,6-bis­[(E)-4-(di­methyl­amino)­styr­yl]pyrimidine
title_full_unstemmed Crystal structure of 2-butyl­sulfanyl-4,6-bis­[(E)-4-(di­methyl­amino)­styr­yl]pyrimidine
title_short Crystal structure of 2-butyl­sulfanyl-4,6-bis­[(E)-4-(di­methyl­amino)­styr­yl]pyrimidine
title_sort crystal structure of 2-butyl­sulfanyl-4,6-bis­[(e)-4-(di­methyl­amino)­styr­yl]pyrimidine
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719932/
https://www.ncbi.nlm.nih.gov/pubmed/26870560
http://dx.doi.org/10.1107/S2056989015021441
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