Crystal structure of 4-(4-meth­oxy­phen­yl)-4′,4′-dimethyl-3-p-tolyl-3′,4′-di­hydro-1′H,3H-spiro­[isoxazole-5,2′-naphthalen]-1′-one

In the title compound, C(28)H(27)NO(3), the cyclo­hexa­none and isoxazole rings have envelope conformations, with the methyl­ene and spiro C atoms as the flaps, respectively. The mean plane of the isoxazole ring is inclined slightly to the p-tolyl ring, making a dihedral angle of 14.20 (9)°, and is...

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Autores principales: Akhazzane, Mohamed, Al Houari, Ghali, El Yazidi, Mohamed, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719934/
https://www.ncbi.nlm.nih.gov/pubmed/26870562
http://dx.doi.org/10.1107/S2056989015022033
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author Akhazzane, Mohamed
Al Houari, Ghali
El Yazidi, Mohamed
Saadi, Mohamed
El Ammari, Lahcen
author_facet Akhazzane, Mohamed
Al Houari, Ghali
El Yazidi, Mohamed
Saadi, Mohamed
El Ammari, Lahcen
author_sort Akhazzane, Mohamed
collection PubMed
description In the title compound, C(28)H(27)NO(3), the cyclo­hexa­none and isoxazole rings have envelope conformations, with the methyl­ene and spiro C atoms as the flaps, respectively. The mean plane of the isoxazole ring is inclined slightly to the p-tolyl ring, making a dihedral angle of 14.20 (9)°, and is nearly perpendicular to the mean plane through the tetra­lone moiety and to the meth­oxy­phenyl ring [dihedral angles = 83.41 (8) and 72.12 (9)°, respectively]. The crystal packing is stabilized mainly by van der Waals forces.
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spelling pubmed-47199342016-02-11 Crystal structure of 4-(4-meth­oxy­phen­yl)-4′,4′-dimethyl-3-p-tolyl-3′,4′-di­hydro-1′H,3H-spiro­[isoxazole-5,2′-naphthalen]-1′-one Akhazzane, Mohamed Al Houari, Ghali El Yazidi, Mohamed Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(28)H(27)NO(3), the cyclo­hexa­none and isoxazole rings have envelope conformations, with the methyl­ene and spiro C atoms as the flaps, respectively. The mean plane of the isoxazole ring is inclined slightly to the p-tolyl ring, making a dihedral angle of 14.20 (9)°, and is nearly perpendicular to the mean plane through the tetra­lone moiety and to the meth­oxy­phenyl ring [dihedral angles = 83.41 (8) and 72.12 (9)°, respectively]. The crystal packing is stabilized mainly by van der Waals forces. International Union of Crystallography 2015-11-21 /pmc/articles/PMC4719934/ /pubmed/26870562 http://dx.doi.org/10.1107/S2056989015022033 Text en © Akhazzane et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Akhazzane, Mohamed
Al Houari, Ghali
El Yazidi, Mohamed
Saadi, Mohamed
El Ammari, Lahcen
Crystal structure of 4-(4-meth­oxy­phen­yl)-4′,4′-dimethyl-3-p-tolyl-3′,4′-di­hydro-1′H,3H-spiro­[isoxazole-5,2′-naphthalen]-1′-one
title Crystal structure of 4-(4-meth­oxy­phen­yl)-4′,4′-dimethyl-3-p-tolyl-3′,4′-di­hydro-1′H,3H-spiro­[isoxazole-5,2′-naphthalen]-1′-one
title_full Crystal structure of 4-(4-meth­oxy­phen­yl)-4′,4′-dimethyl-3-p-tolyl-3′,4′-di­hydro-1′H,3H-spiro­[isoxazole-5,2′-naphthalen]-1′-one
title_fullStr Crystal structure of 4-(4-meth­oxy­phen­yl)-4′,4′-dimethyl-3-p-tolyl-3′,4′-di­hydro-1′H,3H-spiro­[isoxazole-5,2′-naphthalen]-1′-one
title_full_unstemmed Crystal structure of 4-(4-meth­oxy­phen­yl)-4′,4′-dimethyl-3-p-tolyl-3′,4′-di­hydro-1′H,3H-spiro­[isoxazole-5,2′-naphthalen]-1′-one
title_short Crystal structure of 4-(4-meth­oxy­phen­yl)-4′,4′-dimethyl-3-p-tolyl-3′,4′-di­hydro-1′H,3H-spiro­[isoxazole-5,2′-naphthalen]-1′-one
title_sort crystal structure of 4-(4-meth­oxy­phen­yl)-4′,4′-dimethyl-3-p-tolyl-3′,4′-di­hydro-1′h,3h-spiro­[isoxazole-5,2′-naphthalen]-1′-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719934/
https://www.ncbi.nlm.nih.gov/pubmed/26870562
http://dx.doi.org/10.1107/S2056989015022033
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