Crystal structure of (1-eth­oxy­ethyl­idene)di­methyl­aza­nium tetra­phenyl­borate

In the cation of the title salt, C(6)H(14)NO(+)·C(24)H(20)B(−), the C—N bond lengths are 1.297 (2), 1.464 (2) and 1.468 (2) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.309 (2) Å shows double-bond character, pointing towards charge delocalization within the...

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Autores principales: Tiritiris, Ioannis, Saur, Stefan, Kantlehner, Willi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719936/
https://www.ncbi.nlm.nih.gov/pubmed/26870564
http://dx.doi.org/10.1107/S2056989015022252
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author Tiritiris, Ioannis
Saur, Stefan
Kantlehner, Willi
author_facet Tiritiris, Ioannis
Saur, Stefan
Kantlehner, Willi
author_sort Tiritiris, Ioannis
collection PubMed
description In the cation of the title salt, C(6)H(14)NO(+)·C(24)H(20)B(−), the C—N bond lengths are 1.297 (2), 1.464 (2) and 1.468 (2) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.309 (2) Å shows double-bond character, pointing towards charge delocalization within the NCO plane of the iminium ion. In the crystal, C—H⋯π inter­actions between the iminium H atoms and the phenyl C atoms of the anion are present. The phenyl rings form aromatic pockets, in which the iminium ions are embedded.
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spelling pubmed-47199362016-02-11 Crystal structure of (1-eth­oxy­ethyl­idene)di­methyl­aza­nium tetra­phenyl­borate Tiritiris, Ioannis Saur, Stefan Kantlehner, Willi Acta Crystallogr E Crystallogr Commun Data Reports In the cation of the title salt, C(6)H(14)NO(+)·C(24)H(20)B(−), the C—N bond lengths are 1.297 (2), 1.464 (2) and 1.468 (2) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.309 (2) Å shows double-bond character, pointing towards charge delocalization within the NCO plane of the iminium ion. In the crystal, C—H⋯π inter­actions between the iminium H atoms and the phenyl C atoms of the anion are present. The phenyl rings form aromatic pockets, in which the iminium ions are embedded. International Union of Crystallography 2015-11-25 /pmc/articles/PMC4719936/ /pubmed/26870564 http://dx.doi.org/10.1107/S2056989015022252 Text en © Tiritiris et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Tiritiris, Ioannis
Saur, Stefan
Kantlehner, Willi
Crystal structure of (1-eth­oxy­ethyl­idene)di­methyl­aza­nium tetra­phenyl­borate
title Crystal structure of (1-eth­oxy­ethyl­idene)di­methyl­aza­nium tetra­phenyl­borate
title_full Crystal structure of (1-eth­oxy­ethyl­idene)di­methyl­aza­nium tetra­phenyl­borate
title_fullStr Crystal structure of (1-eth­oxy­ethyl­idene)di­methyl­aza­nium tetra­phenyl­borate
title_full_unstemmed Crystal structure of (1-eth­oxy­ethyl­idene)di­methyl­aza­nium tetra­phenyl­borate
title_short Crystal structure of (1-eth­oxy­ethyl­idene)di­methyl­aza­nium tetra­phenyl­borate
title_sort crystal structure of (1-eth­oxy­ethyl­idene)di­methyl­aza­nium tetra­phenyl­borate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719936/
https://www.ncbi.nlm.nih.gov/pubmed/26870564
http://dx.doi.org/10.1107/S2056989015022252
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