Crystal structure of 4-bromo-2-(1H-imidazo[4,5-b]pyridin-2-yl)phenol

In the title compound, C(12)H(8)BrN(3)O, the 4-bromo­phenol ring is coplanar with the planar imidazo[4,5-b]pyridine moiety (r.m.s deviation = 0.015 Å), making a dihedral angle of 1.8 (2)°. There is an intra­molecular O—H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are link...

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Autor principal: Ouari, Kamel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719939/
https://www.ncbi.nlm.nih.gov/pubmed/26870567
http://dx.doi.org/10.1107/S2056989015022197
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author Ouari, Kamel
author_facet Ouari, Kamel
author_sort Ouari, Kamel
collection PubMed
description In the title compound, C(12)H(8)BrN(3)O, the 4-bromo­phenol ring is coplanar with the planar imidazo[4,5-b]pyridine moiety (r.m.s deviation = 0.015 Å), making a dihedral angle of 1.8 (2)°. There is an intra­molecular O—H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are linked via N—H⋯N and O—H⋯Br hydrogen bonds, forming undulating sheets parallel to (10-2). The sheets are linked by π–π inter­actions [inter-centroid distance = 3.7680 (17) Å], involving inversion-related mol­ecules, forming a three-dimensional structure.
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spelling pubmed-47199392016-02-11 Crystal structure of 4-bromo-2-(1H-imidazo[4,5-b]pyridin-2-yl)phenol Ouari, Kamel Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(12)H(8)BrN(3)O, the 4-bromo­phenol ring is coplanar with the planar imidazo[4,5-b]pyridine moiety (r.m.s deviation = 0.015 Å), making a dihedral angle of 1.8 (2)°. There is an intra­molecular O—H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are linked via N—H⋯N and O—H⋯Br hydrogen bonds, forming undulating sheets parallel to (10-2). The sheets are linked by π–π inter­actions [inter-centroid distance = 3.7680 (17) Å], involving inversion-related mol­ecules, forming a three-dimensional structure. International Union of Crystallography 2015-11-28 /pmc/articles/PMC4719939/ /pubmed/26870567 http://dx.doi.org/10.1107/S2056989015022197 Text en © Kamel Ouari 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ouari, Kamel
Crystal structure of 4-bromo-2-(1H-imidazo[4,5-b]pyridin-2-yl)phenol
title Crystal structure of 4-bromo-2-(1H-imidazo[4,5-b]pyridin-2-yl)phenol
title_full Crystal structure of 4-bromo-2-(1H-imidazo[4,5-b]pyridin-2-yl)phenol
title_fullStr Crystal structure of 4-bromo-2-(1H-imidazo[4,5-b]pyridin-2-yl)phenol
title_full_unstemmed Crystal structure of 4-bromo-2-(1H-imidazo[4,5-b]pyridin-2-yl)phenol
title_short Crystal structure of 4-bromo-2-(1H-imidazo[4,5-b]pyridin-2-yl)phenol
title_sort crystal structure of 4-bromo-2-(1h-imidazo[4,5-b]pyridin-2-yl)phenol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719939/
https://www.ncbi.nlm.nih.gov/pubmed/26870567
http://dx.doi.org/10.1107/S2056989015022197
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