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Crystal structure of 4-{[(2,4-di­hydroxy­benzyl­idene)amino]­meth­yl}cyclo­hexane­carb­oxy­lic acid

In the title compound, C(15)H(19)NO(4), the cyclo­hexyl ring adopts a chair conformation with both exocyclic C—C bonds in equatorial orientations. The dihedral angle between the basal plane of cyclo­hexyl ring and the 2,4-di­hydroxy­benzaldehyde moiety is 84.13 (13)°. An intra­molecular O—H⋯N hydrog...

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Detalles Bibliográficos
Autores principales: Danish, Muhammad, Akbar, Saba, Tahir, Muhammad Nawaz, Butt, Rabia Ayub, Ashfaq, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719941/
https://www.ncbi.nlm.nih.gov/pubmed/26870569
http://dx.doi.org/10.1107/S2056989015022343
Descripción
Sumario:In the title compound, C(15)H(19)NO(4), the cyclo­hexyl ring adopts a chair conformation with both exocyclic C—C bonds in equatorial orientations. The dihedral angle between the basal plane of cyclo­hexyl ring and the 2,4-di­hydroxy­benzaldehyde moiety is 84.13 (13)°. An intra­molecular O—H⋯N hydrogen bonds closes an S(6) ring. In the crystal, O(c)—H⋯O(p) (c = carb­oxy­lic acid, p = phenol) hydrogen bonds link the mol­ecules into [100] C(13) chains whereas an O(p)—H⋯O(c) hydrogen bond generates [101] C(15) chains. Together, these bonds generate (010) sheets incorporating R (2) (2)(20) loops. Weak C—H⋯O and C—H⋯π inter­actions also occur.