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Crystal structure of 4-{[(2,4-di­hydroxy­benzyl­idene)amino]­meth­yl}cyclo­hexane­carb­oxy­lic acid

In the title compound, C(15)H(19)NO(4), the cyclo­hexyl ring adopts a chair conformation with both exocyclic C—C bonds in equatorial orientations. The dihedral angle between the basal plane of cyclo­hexyl ring and the 2,4-di­hydroxy­benzaldehyde moiety is 84.13 (13)°. An intra­molecular O—H⋯N hydrog...

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Autores principales: Danish, Muhammad, Akbar, Saba, Tahir, Muhammad Nawaz, Butt, Rabia Ayub, Ashfaq, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719941/
https://www.ncbi.nlm.nih.gov/pubmed/26870569
http://dx.doi.org/10.1107/S2056989015022343
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author Danish, Muhammad
Akbar, Saba
Tahir, Muhammad Nawaz
Butt, Rabia Ayub
Ashfaq, Muhammad
author_facet Danish, Muhammad
Akbar, Saba
Tahir, Muhammad Nawaz
Butt, Rabia Ayub
Ashfaq, Muhammad
author_sort Danish, Muhammad
collection PubMed
description In the title compound, C(15)H(19)NO(4), the cyclo­hexyl ring adopts a chair conformation with both exocyclic C—C bonds in equatorial orientations. The dihedral angle between the basal plane of cyclo­hexyl ring and the 2,4-di­hydroxy­benzaldehyde moiety is 84.13 (13)°. An intra­molecular O—H⋯N hydrogen bonds closes an S(6) ring. In the crystal, O(c)—H⋯O(p) (c = carb­oxy­lic acid, p = phenol) hydrogen bonds link the mol­ecules into [100] C(13) chains whereas an O(p)—H⋯O(c) hydrogen bond generates [101] C(15) chains. Together, these bonds generate (010) sheets incorporating R (2) (2)(20) loops. Weak C—H⋯O and C—H⋯π inter­actions also occur.
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spelling pubmed-47199412016-02-11 Crystal structure of 4-{[(2,4-di­hydroxy­benzyl­idene)amino]­meth­yl}cyclo­hexane­carb­oxy­lic acid Danish, Muhammad Akbar, Saba Tahir, Muhammad Nawaz Butt, Rabia Ayub Ashfaq, Muhammad Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(15)H(19)NO(4), the cyclo­hexyl ring adopts a chair conformation with both exocyclic C—C bonds in equatorial orientations. The dihedral angle between the basal plane of cyclo­hexyl ring and the 2,4-di­hydroxy­benzaldehyde moiety is 84.13 (13)°. An intra­molecular O—H⋯N hydrogen bonds closes an S(6) ring. In the crystal, O(c)—H⋯O(p) (c = carb­oxy­lic acid, p = phenol) hydrogen bonds link the mol­ecules into [100] C(13) chains whereas an O(p)—H⋯O(c) hydrogen bond generates [101] C(15) chains. Together, these bonds generate (010) sheets incorporating R (2) (2)(20) loops. Weak C—H⋯O and C—H⋯π inter­actions also occur. International Union of Crystallography 2015-11-28 /pmc/articles/PMC4719941/ /pubmed/26870569 http://dx.doi.org/10.1107/S2056989015022343 Text en © Danish et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Danish, Muhammad
Akbar, Saba
Tahir, Muhammad Nawaz
Butt, Rabia Ayub
Ashfaq, Muhammad
Crystal structure of 4-{[(2,4-di­hydroxy­benzyl­idene)amino]­meth­yl}cyclo­hexane­carb­oxy­lic acid
title Crystal structure of 4-{[(2,4-di­hydroxy­benzyl­idene)amino]­meth­yl}cyclo­hexane­carb­oxy­lic acid
title_full Crystal structure of 4-{[(2,4-di­hydroxy­benzyl­idene)amino]­meth­yl}cyclo­hexane­carb­oxy­lic acid
title_fullStr Crystal structure of 4-{[(2,4-di­hydroxy­benzyl­idene)amino]­meth­yl}cyclo­hexane­carb­oxy­lic acid
title_full_unstemmed Crystal structure of 4-{[(2,4-di­hydroxy­benzyl­idene)amino]­meth­yl}cyclo­hexane­carb­oxy­lic acid
title_short Crystal structure of 4-{[(2,4-di­hydroxy­benzyl­idene)amino]­meth­yl}cyclo­hexane­carb­oxy­lic acid
title_sort crystal structure of 4-{[(2,4-di­hydroxy­benzyl­idene)amino]­meth­yl}cyclo­hexane­carb­oxy­lic acid
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719941/
https://www.ncbi.nlm.nih.gov/pubmed/26870569
http://dx.doi.org/10.1107/S2056989015022343
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