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Crystal structure of 4-{[(2,4-dihydroxybenzylidene)amino]methyl}cyclohexanecarboxylic acid
In the title compound, C(15)H(19)NO(4), the cyclohexyl ring adopts a chair conformation with both exocyclic C—C bonds in equatorial orientations. The dihedral angle between the basal plane of cyclohexyl ring and the 2,4-dihydroxybenzaldehyde moiety is 84.13 (13)°. An intramolecular O—H⋯N hydrog...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719941/ https://www.ncbi.nlm.nih.gov/pubmed/26870569 http://dx.doi.org/10.1107/S2056989015022343 |
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author | Danish, Muhammad Akbar, Saba Tahir, Muhammad Nawaz Butt, Rabia Ayub Ashfaq, Muhammad |
author_facet | Danish, Muhammad Akbar, Saba Tahir, Muhammad Nawaz Butt, Rabia Ayub Ashfaq, Muhammad |
author_sort | Danish, Muhammad |
collection | PubMed |
description | In the title compound, C(15)H(19)NO(4), the cyclohexyl ring adopts a chair conformation with both exocyclic C—C bonds in equatorial orientations. The dihedral angle between the basal plane of cyclohexyl ring and the 2,4-dihydroxybenzaldehyde moiety is 84.13 (13)°. An intramolecular O—H⋯N hydrogen bonds closes an S(6) ring. In the crystal, O(c)—H⋯O(p) (c = carboxylic acid, p = phenol) hydrogen bonds link the molecules into [100] C(13) chains whereas an O(p)—H⋯O(c) hydrogen bond generates [101] C(15) chains. Together, these bonds generate (010) sheets incorporating R (2) (2)(20) loops. Weak C—H⋯O and C—H⋯π interactions also occur. |
format | Online Article Text |
id | pubmed-4719941 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-47199412016-02-11 Crystal structure of 4-{[(2,4-dihydroxybenzylidene)amino]methyl}cyclohexanecarboxylic acid Danish, Muhammad Akbar, Saba Tahir, Muhammad Nawaz Butt, Rabia Ayub Ashfaq, Muhammad Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(15)H(19)NO(4), the cyclohexyl ring adopts a chair conformation with both exocyclic C—C bonds in equatorial orientations. The dihedral angle between the basal plane of cyclohexyl ring and the 2,4-dihydroxybenzaldehyde moiety is 84.13 (13)°. An intramolecular O—H⋯N hydrogen bonds closes an S(6) ring. In the crystal, O(c)—H⋯O(p) (c = carboxylic acid, p = phenol) hydrogen bonds link the molecules into [100] C(13) chains whereas an O(p)—H⋯O(c) hydrogen bond generates [101] C(15) chains. Together, these bonds generate (010) sheets incorporating R (2) (2)(20) loops. Weak C—H⋯O and C—H⋯π interactions also occur. International Union of Crystallography 2015-11-28 /pmc/articles/PMC4719941/ /pubmed/26870569 http://dx.doi.org/10.1107/S2056989015022343 Text en © Danish et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Danish, Muhammad Akbar, Saba Tahir, Muhammad Nawaz Butt, Rabia Ayub Ashfaq, Muhammad Crystal structure of 4-{[(2,4-dihydroxybenzylidene)amino]methyl}cyclohexanecarboxylic acid |
title | Crystal structure of 4-{[(2,4-dihydroxybenzylidene)amino]methyl}cyclohexanecarboxylic acid |
title_full | Crystal structure of 4-{[(2,4-dihydroxybenzylidene)amino]methyl}cyclohexanecarboxylic acid |
title_fullStr | Crystal structure of 4-{[(2,4-dihydroxybenzylidene)amino]methyl}cyclohexanecarboxylic acid |
title_full_unstemmed | Crystal structure of 4-{[(2,4-dihydroxybenzylidene)amino]methyl}cyclohexanecarboxylic acid |
title_short | Crystal structure of 4-{[(2,4-dihydroxybenzylidene)amino]methyl}cyclohexanecarboxylic acid |
title_sort | crystal structure of 4-{[(2,4-dihydroxybenzylidene)amino]methyl}cyclohexanecarboxylic acid |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719941/ https://www.ncbi.nlm.nih.gov/pubmed/26870569 http://dx.doi.org/10.1107/S2056989015022343 |
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