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Crystal structure of (E)-5-benz­yloxy-2-{[(4-nitro­phen­yl)imino]­meth­yl}phenol

In the title compound, C(20)H(16)N(2)O(4), the mol­ecule adopts an E conformation about the N=C bond. There is an intra­molecular O—H⋯N hydrogen bond forming an S(6) ring motif. The nitro­benzene and benz­yloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)°, respectively...

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Detalles Bibliográficos
Autores principales: Ghichi, Nadir, Benaouida, Mohamed Amine, Benboudiaf, Ali, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719944/
https://www.ncbi.nlm.nih.gov/pubmed/26870463
http://dx.doi.org/10.1107/S2056989015022173
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author Ghichi, Nadir
Benaouida, Mohamed Amine
Benboudiaf, Ali
Merazig, Hocine
author_facet Ghichi, Nadir
Benaouida, Mohamed Amine
Benboudiaf, Ali
Merazig, Hocine
author_sort Ghichi, Nadir
collection PubMed
description In the title compound, C(20)H(16)N(2)O(4), the mol­ecule adopts an E conformation about the N=C bond. There is an intra­molecular O—H⋯N hydrogen bond forming an S(6) ring motif. The nitro­benzene and benz­yloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)°, respectively, and to one another by 31.40 (12)°. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming zigzag chains along [001]. Within the chains there are C—H⋯π inter­actions present. The chains are linked via π–π inter­actions [inter-centroid distance = 3.7048 (15) Å], forming slabs parallel to the bc plane.
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spelling pubmed-47199442016-02-11 Crystal structure of (E)-5-benz­yloxy-2-{[(4-nitro­phen­yl)imino]­meth­yl}phenol Ghichi, Nadir Benaouida, Mohamed Amine Benboudiaf, Ali Merazig, Hocine Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(20)H(16)N(2)O(4), the mol­ecule adopts an E conformation about the N=C bond. There is an intra­molecular O—H⋯N hydrogen bond forming an S(6) ring motif. The nitro­benzene and benz­yloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)°, respectively, and to one another by 31.40 (12)°. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming zigzag chains along [001]. Within the chains there are C—H⋯π inter­actions present. The chains are linked via π–π inter­actions [inter-centroid distance = 3.7048 (15) Å], forming slabs parallel to the bc plane. International Union of Crystallography 2015-11-28 /pmc/articles/PMC4719944/ /pubmed/26870463 http://dx.doi.org/10.1107/S2056989015022173 Text en © Ghichi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ghichi, Nadir
Benaouida, Mohamed Amine
Benboudiaf, Ali
Merazig, Hocine
Crystal structure of (E)-5-benz­yloxy-2-{[(4-nitro­phen­yl)imino]­meth­yl}phenol
title Crystal structure of (E)-5-benz­yloxy-2-{[(4-nitro­phen­yl)imino]­meth­yl}phenol
title_full Crystal structure of (E)-5-benz­yloxy-2-{[(4-nitro­phen­yl)imino]­meth­yl}phenol
title_fullStr Crystal structure of (E)-5-benz­yloxy-2-{[(4-nitro­phen­yl)imino]­meth­yl}phenol
title_full_unstemmed Crystal structure of (E)-5-benz­yloxy-2-{[(4-nitro­phen­yl)imino]­meth­yl}phenol
title_short Crystal structure of (E)-5-benz­yloxy-2-{[(4-nitro­phen­yl)imino]­meth­yl}phenol
title_sort crystal structure of (e)-5-benz­yloxy-2-{[(4-nitro­phen­yl)imino]­meth­yl}phenol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719944/
https://www.ncbi.nlm.nih.gov/pubmed/26870463
http://dx.doi.org/10.1107/S2056989015022173
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