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Crystal structure of (E)-5-benzyloxy-2-{[(4-nitrophenyl)imino]methyl}phenol
In the title compound, C(20)H(16)N(2)O(4), the molecule adopts an E conformation about the N=C bond. There is an intramolecular O—H⋯N hydrogen bond forming an S(6) ring motif. The nitrobenzene and benzyloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)°, respectively...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719944/ https://www.ncbi.nlm.nih.gov/pubmed/26870463 http://dx.doi.org/10.1107/S2056989015022173 |
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author | Ghichi, Nadir Benaouida, Mohamed Amine Benboudiaf, Ali Merazig, Hocine |
author_facet | Ghichi, Nadir Benaouida, Mohamed Amine Benboudiaf, Ali Merazig, Hocine |
author_sort | Ghichi, Nadir |
collection | PubMed |
description | In the title compound, C(20)H(16)N(2)O(4), the molecule adopts an E conformation about the N=C bond. There is an intramolecular O—H⋯N hydrogen bond forming an S(6) ring motif. The nitrobenzene and benzyloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)°, respectively, and to one another by 31.40 (12)°. In the crystal, molecules are linked via C—H⋯O hydrogen bonds, forming zigzag chains along [001]. Within the chains there are C—H⋯π interactions present. The chains are linked via π–π interactions [inter-centroid distance = 3.7048 (15) Å], forming slabs parallel to the bc plane. |
format | Online Article Text |
id | pubmed-4719944 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-47199442016-02-11 Crystal structure of (E)-5-benzyloxy-2-{[(4-nitrophenyl)imino]methyl}phenol Ghichi, Nadir Benaouida, Mohamed Amine Benboudiaf, Ali Merazig, Hocine Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(20)H(16)N(2)O(4), the molecule adopts an E conformation about the N=C bond. There is an intramolecular O—H⋯N hydrogen bond forming an S(6) ring motif. The nitrobenzene and benzyloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)°, respectively, and to one another by 31.40 (12)°. In the crystal, molecules are linked via C—H⋯O hydrogen bonds, forming zigzag chains along [001]. Within the chains there are C—H⋯π interactions present. The chains are linked via π–π interactions [inter-centroid distance = 3.7048 (15) Å], forming slabs parallel to the bc plane. International Union of Crystallography 2015-11-28 /pmc/articles/PMC4719944/ /pubmed/26870463 http://dx.doi.org/10.1107/S2056989015022173 Text en © Ghichi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Ghichi, Nadir Benaouida, Mohamed Amine Benboudiaf, Ali Merazig, Hocine Crystal structure of (E)-5-benzyloxy-2-{[(4-nitrophenyl)imino]methyl}phenol |
title | Crystal structure of (E)-5-benzyloxy-2-{[(4-nitrophenyl)imino]methyl}phenol |
title_full | Crystal structure of (E)-5-benzyloxy-2-{[(4-nitrophenyl)imino]methyl}phenol |
title_fullStr | Crystal structure of (E)-5-benzyloxy-2-{[(4-nitrophenyl)imino]methyl}phenol |
title_full_unstemmed | Crystal structure of (E)-5-benzyloxy-2-{[(4-nitrophenyl)imino]methyl}phenol |
title_short | Crystal structure of (E)-5-benzyloxy-2-{[(4-nitrophenyl)imino]methyl}phenol |
title_sort | crystal structure of (e)-5-benzyloxy-2-{[(4-nitrophenyl)imino]methyl}phenol |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719944/ https://www.ncbi.nlm.nih.gov/pubmed/26870463 http://dx.doi.org/10.1107/S2056989015022173 |
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