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Crystal structure of (tert-butylcarbamoyl)(4-chloro-2-oxo-2H-chromen-3-yl)methyl acetate
In the title compound, C(17)H(18)ClNO(5), which was synthesized by reacting 4-chloro-3-formylcoumarin, acetic acid and tert-butyl isocyanide, the acetamido side chain is convoluted with ring-to-side chain C—C—C—C, C—C—C—N and C—C—N—C torsion angles of −123.30 (14), −135.73 (12) and 176.10 (12)°, re...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719945/ https://www.ncbi.nlm.nih.gov/pubmed/26870464 http://dx.doi.org/10.1107/S2056989015021982 |
Sumario: | In the title compound, C(17)H(18)ClNO(5), which was synthesized by reacting 4-chloro-3-formylcoumarin, acetic acid and tert-butyl isocyanide, the acetamido side chain is convoluted with ring-to-side chain C—C—C—C, C—C—C—N and C—C—N—C torsion angles of −123.30 (14), −135.73 (12) and 176.10 (12)°, respectively. In the crystal, N—H⋯O and weak C—H⋯O hydrogen bonds are present, which together with π–π coumarin-ring interactions [ring centroid separations = 3.4582 (8) and 3.6421 (9) Å], give rise to a layered structure lying parallel to (001). |
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