Crystal structure of (Z)-3-allyl-5-(3-bromo­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one

In the title compound, C(13)H(10)BrNOS(2), the rhodanine (systematic name: 2-sulfanyl­idene-1,3-thia­zolidin-4-one) and the 3-bromo­benzyl­idene ring systems are inclined slightly, forming a dihedral angle of 5.86 (12)°. The rhodanine moiety is linked to an allyl group at the N atom and to the 3-bro...

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Autores principales: El Ajlaoui, Rahhal, Rakib, El Mostapha, Forsal, Issam, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719950/
https://www.ncbi.nlm.nih.gov/pubmed/26870469
http://dx.doi.org/10.1107/S2056989015022884
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author El Ajlaoui, Rahhal
Rakib, El Mostapha
Forsal, Issam
Saadi, Mohamed
El Ammari, Lahcen
author_facet El Ajlaoui, Rahhal
Rakib, El Mostapha
Forsal, Issam
Saadi, Mohamed
El Ammari, Lahcen
author_sort El Ajlaoui, Rahhal
collection PubMed
description In the title compound, C(13)H(10)BrNOS(2), the rhodanine (systematic name: 2-sulfanyl­idene-1,3-thia­zolidin-4-one) and the 3-bromo­benzyl­idene ring systems are inclined slightly, forming a dihedral angle of 5.86 (12)°. The rhodanine moiety is linked to an allyl group at the N atom and to the 3-bromo­benzyl­idene ring system. The allyl group, C=C—C, is nearly perpendicular to the mean plane through the rhodanine ring, maling a dihedral angle of 87.2 (5)°. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif.
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spelling pubmed-47199502016-02-11 Crystal structure of (Z)-3-allyl-5-(3-bromo­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one El Ajlaoui, Rahhal Rakib, El Mostapha Forsal, Issam Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(13)H(10)BrNOS(2), the rhodanine (systematic name: 2-sulfanyl­idene-1,3-thia­zolidin-4-one) and the 3-bromo­benzyl­idene ring systems are inclined slightly, forming a dihedral angle of 5.86 (12)°. The rhodanine moiety is linked to an allyl group at the N atom and to the 3-bromo­benzyl­idene ring system. The allyl group, C=C—C, is nearly perpendicular to the mean plane through the rhodanine ring, maling a dihedral angle of 87.2 (5)°. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. International Union of Crystallography 2015-12-06 /pmc/articles/PMC4719950/ /pubmed/26870469 http://dx.doi.org/10.1107/S2056989015022884 Text en © El Ajlaoui et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
El Ajlaoui, Rahhal
Rakib, El Mostapha
Forsal, Issam
Saadi, Mohamed
El Ammari, Lahcen
Crystal structure of (Z)-3-allyl-5-(3-bromo­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title Crystal structure of (Z)-3-allyl-5-(3-bromo­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title_full Crystal structure of (Z)-3-allyl-5-(3-bromo­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title_fullStr Crystal structure of (Z)-3-allyl-5-(3-bromo­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title_full_unstemmed Crystal structure of (Z)-3-allyl-5-(3-bromo­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title_short Crystal structure of (Z)-3-allyl-5-(3-bromo­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title_sort crystal structure of (z)-3-allyl-5-(3-bromo­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719950/
https://www.ncbi.nlm.nih.gov/pubmed/26870469
http://dx.doi.org/10.1107/S2056989015022884
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