Crystal structure of (Z)-3-allyl-5-(4-chloro­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one

In the title compound, C(13)H(10)ClNOS(2), the dihedral angle between the rhodanine (r.m.s. deviation = 0.008 Å) and 4-chloro­benzyl­idene rings is 1.79 (11)°. The allyl group attached to the N atom, which lies almost perpendicular to the rhodanine ring, is disordered over two orientations in a 0.51...

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Autores principales: El Ajlaoui, Rahhal, Rakib, El Mostapha, Mojahidi, Souad, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719951/
https://www.ncbi.nlm.nih.gov/pubmed/26870470
http://dx.doi.org/10.1107/S2056989015022689
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author El Ajlaoui, Rahhal
Rakib, El Mostapha
Mojahidi, Souad
Saadi, Mohamed
El Ammari, Lahcen
author_facet El Ajlaoui, Rahhal
Rakib, El Mostapha
Mojahidi, Souad
Saadi, Mohamed
El Ammari, Lahcen
author_sort El Ajlaoui, Rahhal
collection PubMed
description In the title compound, C(13)H(10)ClNOS(2), the dihedral angle between the rhodanine (r.m.s. deviation = 0.008 Å) and 4-chloro­benzyl­idene rings is 1.79 (11)°. The allyl group attached to the N atom, which lies almost perpendicular to the rhodanine ring, is disordered over two orientations in a 0.519 (13):0.481 (13) ratio. A short intra­molecular C—H⋯S inter­action closes an S(6) ring. In the crystal, mol­ecules are linked by π–π stacking inter­actions [centroid–centroid separation = 3.600 (15) Å], generating inversion dimers.
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spelling pubmed-47199512016-02-11 Crystal structure of (Z)-3-allyl-5-(4-chloro­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one El Ajlaoui, Rahhal Rakib, El Mostapha Mojahidi, Souad Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(13)H(10)ClNOS(2), the dihedral angle between the rhodanine (r.m.s. deviation = 0.008 Å) and 4-chloro­benzyl­idene rings is 1.79 (11)°. The allyl group attached to the N atom, which lies almost perpendicular to the rhodanine ring, is disordered over two orientations in a 0.519 (13):0.481 (13) ratio. A short intra­molecular C—H⋯S inter­action closes an S(6) ring. In the crystal, mol­ecules are linked by π–π stacking inter­actions [centroid–centroid separation = 3.600 (15) Å], generating inversion dimers. International Union of Crystallography 2015-12-06 /pmc/articles/PMC4719951/ /pubmed/26870470 http://dx.doi.org/10.1107/S2056989015022689 Text en © El Ajlaoui et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
El Ajlaoui, Rahhal
Rakib, El Mostapha
Mojahidi, Souad
Saadi, Mohamed
El Ammari, Lahcen
Crystal structure of (Z)-3-allyl-5-(4-chloro­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title Crystal structure of (Z)-3-allyl-5-(4-chloro­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title_full Crystal structure of (Z)-3-allyl-5-(4-chloro­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title_fullStr Crystal structure of (Z)-3-allyl-5-(4-chloro­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title_full_unstemmed Crystal structure of (Z)-3-allyl-5-(4-chloro­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title_short Crystal structure of (Z)-3-allyl-5-(4-chloro­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
title_sort crystal structure of (z)-3-allyl-5-(4-chloro­benzyl­idene)-2-sulfanyl­idene-1,3-thia­zolidin-4-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719951/
https://www.ncbi.nlm.nih.gov/pubmed/26870470
http://dx.doi.org/10.1107/S2056989015022689
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