Crystal structure of (1R,3S,8R,11R)-11-acetyl-3,7,7-trimethyl-10-oxatri­cyclo­[6.4.0.0(1,3)]dodecan-9-one

The title compound, C(16)H(24)O(3), is built up from three fused rings, a six-membered, a seven-membered and a three-membered ring. The absolute configuration of the title compound was determined as (1R,3S,8R,11R) based on the synthetic pathway. The six-membered ring has an half-chair conformation w...

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Autores principales: Bismoussa, Abdoullah, Ait Itto, My Youssef, Daran, Jean-Claude, Auhmani, Abdelwahed, Auhmani, Aziz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719952/
https://www.ncbi.nlm.nih.gov/pubmed/26870471
http://dx.doi.org/10.1107/S2056989015022847
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author Bismoussa, Abdoullah
Ait Itto, My Youssef
Daran, Jean-Claude
Auhmani, Abdelwahed
Auhmani, Aziz
author_facet Bismoussa, Abdoullah
Ait Itto, My Youssef
Daran, Jean-Claude
Auhmani, Abdelwahed
Auhmani, Aziz
author_sort Bismoussa, Abdoullah
collection PubMed
description The title compound, C(16)H(24)O(3), is built up from three fused rings, a six-membered, a seven-membered and a three-membered ring. The absolute configuration of the title compound was determined as (1R,3S,8R,11R) based on the synthetic pathway. The six-membered ring has an half-chair conformation whereas the seven-membered ring displays a boat conformation. In the cyrstal, C—H⋯O hydrogen bonds build up a two-dimensional network parallel to (0 0 1). The crystal studied was an inversion twin with a minor twin component of 34%.
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spelling pubmed-47199522016-02-11 Crystal structure of (1R,3S,8R,11R)-11-acetyl-3,7,7-trimethyl-10-oxatri­cyclo­[6.4.0.0(1,3)]dodecan-9-one Bismoussa, Abdoullah Ait Itto, My Youssef Daran, Jean-Claude Auhmani, Abdelwahed Auhmani, Aziz Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(16)H(24)O(3), is built up from three fused rings, a six-membered, a seven-membered and a three-membered ring. The absolute configuration of the title compound was determined as (1R,3S,8R,11R) based on the synthetic pathway. The six-membered ring has an half-chair conformation whereas the seven-membered ring displays a boat conformation. In the cyrstal, C—H⋯O hydrogen bonds build up a two-dimensional network parallel to (0 0 1). The crystal studied was an inversion twin with a minor twin component of 34%. International Union of Crystallography 2015-12-06 /pmc/articles/PMC4719952/ /pubmed/26870471 http://dx.doi.org/10.1107/S2056989015022847 Text en © Bismoussa et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Bismoussa, Abdoullah
Ait Itto, My Youssef
Daran, Jean-Claude
Auhmani, Abdelwahed
Auhmani, Aziz
Crystal structure of (1R,3S,8R,11R)-11-acetyl-3,7,7-trimethyl-10-oxatri­cyclo­[6.4.0.0(1,3)]dodecan-9-one
title Crystal structure of (1R,3S,8R,11R)-11-acetyl-3,7,7-trimethyl-10-oxatri­cyclo­[6.4.0.0(1,3)]dodecan-9-one
title_full Crystal structure of (1R,3S,8R,11R)-11-acetyl-3,7,7-trimethyl-10-oxatri­cyclo­[6.4.0.0(1,3)]dodecan-9-one
title_fullStr Crystal structure of (1R,3S,8R,11R)-11-acetyl-3,7,7-trimethyl-10-oxatri­cyclo­[6.4.0.0(1,3)]dodecan-9-one
title_full_unstemmed Crystal structure of (1R,3S,8R,11R)-11-acetyl-3,7,7-trimethyl-10-oxatri­cyclo­[6.4.0.0(1,3)]dodecan-9-one
title_short Crystal structure of (1R,3S,8R,11R)-11-acetyl-3,7,7-trimethyl-10-oxatri­cyclo­[6.4.0.0(1,3)]dodecan-9-one
title_sort crystal structure of (1r,3s,8r,11r)-11-acetyl-3,7,7-trimethyl-10-oxatri­cyclo­[6.4.0.0(1,3)]dodecan-9-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719952/
https://www.ncbi.nlm.nih.gov/pubmed/26870471
http://dx.doi.org/10.1107/S2056989015022847
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