Crystal structure of (tert-butyl­dimethyl­sil­yl)tri­phenyl­germane, Ph(3)Ge-SiMe(2)(t-Bu)

In the title compound, Ph(3)Ge-SiMe(2)(t-Bu) or C(24)H(30)GeSi, the Si and Ge atoms both possess a tetra­hedral coordination environment with C—E—C (E = Si, Ge) angles in the range 104.47 (5)–114.67 (5)°. The mol­ecule adopts an eclipsed conformation, with three torsion angles less than 29.5°. In th...

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Autores principales: Zaitsev, Kirill V., Zaitseva, Galina S., Karlov, Sergey S., Korlyukov, Alexander A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719953/
https://www.ncbi.nlm.nih.gov/pubmed/26870472
http://dx.doi.org/10.1107/S2056989015022872
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author Zaitsev, Kirill V.
Zaitseva, Galina S.
Karlov, Sergey S.
Korlyukov, Alexander A.
author_facet Zaitsev, Kirill V.
Zaitseva, Galina S.
Karlov, Sergey S.
Korlyukov, Alexander A.
author_sort Zaitsev, Kirill V.
collection PubMed
description In the title compound, Ph(3)Ge-SiMe(2)(t-Bu) or C(24)H(30)GeSi, the Si and Ge atoms both possess a tetra­hedral coordination environment with C—E—C (E = Si, Ge) angles in the range 104.47 (5)–114.67 (5)°. The mol­ecule adopts an eclipsed conformation, with three torsion angles less than 29.5°. In the crystal, neighbouring mol­ecules are combined to dimers by six T-shaped C—H⋯π inter­actions, forming sixfold phenyl embraces (6PE).
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spelling pubmed-47199532016-02-11 Crystal structure of (tert-butyl­dimethyl­sil­yl)tri­phenyl­germane, Ph(3)Ge-SiMe(2)(t-Bu) Zaitsev, Kirill V. Zaitseva, Galina S. Karlov, Sergey S. Korlyukov, Alexander A. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, Ph(3)Ge-SiMe(2)(t-Bu) or C(24)H(30)GeSi, the Si and Ge atoms both possess a tetra­hedral coordination environment with C—E—C (E = Si, Ge) angles in the range 104.47 (5)–114.67 (5)°. The mol­ecule adopts an eclipsed conformation, with three torsion angles less than 29.5°. In the crystal, neighbouring mol­ecules are combined to dimers by six T-shaped C—H⋯π inter­actions, forming sixfold phenyl embraces (6PE). International Union of Crystallography 2015-12-06 /pmc/articles/PMC4719953/ /pubmed/26870472 http://dx.doi.org/10.1107/S2056989015022872 Text en © Zaitsev et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Zaitsev, Kirill V.
Zaitseva, Galina S.
Karlov, Sergey S.
Korlyukov, Alexander A.
Crystal structure of (tert-butyl­dimethyl­sil­yl)tri­phenyl­germane, Ph(3)Ge-SiMe(2)(t-Bu)
title Crystal structure of (tert-butyl­dimethyl­sil­yl)tri­phenyl­germane, Ph(3)Ge-SiMe(2)(t-Bu)
title_full Crystal structure of (tert-butyl­dimethyl­sil­yl)tri­phenyl­germane, Ph(3)Ge-SiMe(2)(t-Bu)
title_fullStr Crystal structure of (tert-butyl­dimethyl­sil­yl)tri­phenyl­germane, Ph(3)Ge-SiMe(2)(t-Bu)
title_full_unstemmed Crystal structure of (tert-butyl­dimethyl­sil­yl)tri­phenyl­germane, Ph(3)Ge-SiMe(2)(t-Bu)
title_short Crystal structure of (tert-butyl­dimethyl­sil­yl)tri­phenyl­germane, Ph(3)Ge-SiMe(2)(t-Bu)
title_sort crystal structure of (tert-butyl­dimethyl­sil­yl)tri­phenyl­germane, ph(3)ge-sime(2)(t-bu)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719953/
https://www.ncbi.nlm.nih.gov/pubmed/26870472
http://dx.doi.org/10.1107/S2056989015022872
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