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Crystal structure of (E)-diethyl 2-[(1-phenyl­sulfonyl-1H-indol-3-yl)methyl­idene]succinate

In the title compound, C(23)H(23)NO(6)S, the phenyl ring is perpendicular [dihedral angle = 89.34 (9)°] to the indole ring system. In the mol­ecule, the eth­oxy groups are each disordered over two sets of sites with occupancy ratios of 0.671 (6):0.329 (6) and 0.75 (3):0.25 (3). The mol­ecular confor...

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Autores principales: Umadevi, M., Raju, Potharaju, Yamuna, R., Mohanakrishnan, Arasambattu K., Chakkaravarthi, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719962/
https://www.ncbi.nlm.nih.gov/pubmed/26870481
http://dx.doi.org/10.1107/S2056989015023075
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author Umadevi, M.
Raju, Potharaju
Yamuna, R.
Mohanakrishnan, Arasambattu K.
Chakkaravarthi, G.
author_facet Umadevi, M.
Raju, Potharaju
Yamuna, R.
Mohanakrishnan, Arasambattu K.
Chakkaravarthi, G.
author_sort Umadevi, M.
collection PubMed
description In the title compound, C(23)H(23)NO(6)S, the phenyl ring is perpendicular [dihedral angle = 89.34 (9)°] to the indole ring system. In the mol­ecule, the eth­oxy groups are each disordered over two sets of sites with occupancy ratios of 0.671 (6):0.329 (6) and 0.75 (3):0.25 (3). The mol­ecular conformation is consolidated by a weak C—H⋯O interaction, which generates an S(6) graph–set motif. The packing of the mol­ecules in the crystal structure features weak C—H⋯π inter­actions.
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spelling pubmed-47199622016-02-11 Crystal structure of (E)-diethyl 2-[(1-phenyl­sulfonyl-1H-indol-3-yl)methyl­idene]succinate Umadevi, M. Raju, Potharaju Yamuna, R. Mohanakrishnan, Arasambattu K. Chakkaravarthi, G. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(23)H(23)NO(6)S, the phenyl ring is perpendicular [dihedral angle = 89.34 (9)°] to the indole ring system. In the mol­ecule, the eth­oxy groups are each disordered over two sets of sites with occupancy ratios of 0.671 (6):0.329 (6) and 0.75 (3):0.25 (3). The mol­ecular conformation is consolidated by a weak C—H⋯O interaction, which generates an S(6) graph–set motif. The packing of the mol­ecules in the crystal structure features weak C—H⋯π inter­actions. International Union of Crystallography 2015-12-09 /pmc/articles/PMC4719962/ /pubmed/26870481 http://dx.doi.org/10.1107/S2056989015023075 Text en © Umadevi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Umadevi, M.
Raju, Potharaju
Yamuna, R.
Mohanakrishnan, Arasambattu K.
Chakkaravarthi, G.
Crystal structure of (E)-diethyl 2-[(1-phenyl­sulfonyl-1H-indol-3-yl)methyl­idene]succinate
title Crystal structure of (E)-diethyl 2-[(1-phenyl­sulfonyl-1H-indol-3-yl)methyl­idene]succinate
title_full Crystal structure of (E)-diethyl 2-[(1-phenyl­sulfonyl-1H-indol-3-yl)methyl­idene]succinate
title_fullStr Crystal structure of (E)-diethyl 2-[(1-phenyl­sulfonyl-1H-indol-3-yl)methyl­idene]succinate
title_full_unstemmed Crystal structure of (E)-diethyl 2-[(1-phenyl­sulfonyl-1H-indol-3-yl)methyl­idene]succinate
title_short Crystal structure of (E)-diethyl 2-[(1-phenyl­sulfonyl-1H-indol-3-yl)methyl­idene]succinate
title_sort crystal structure of (e)-diethyl 2-[(1-phenyl­sulfonyl-1h-indol-3-yl)methyl­idene]succinate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719962/
https://www.ncbi.nlm.nih.gov/pubmed/26870481
http://dx.doi.org/10.1107/S2056989015023075
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