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Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate
In the title compound, C(23)H(23)NO(6)S, the phenyl ring is perpendicular [dihedral angle = 89.34 (9)°] to the indole ring system. In the molecule, the ethoxy groups are each disordered over two sets of sites with occupancy ratios of 0.671 (6):0.329 (6) and 0.75 (3):0.25 (3). The molecular confor...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719962/ https://www.ncbi.nlm.nih.gov/pubmed/26870481 http://dx.doi.org/10.1107/S2056989015023075 |
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author | Umadevi, M. Raju, Potharaju Yamuna, R. Mohanakrishnan, Arasambattu K. Chakkaravarthi, G. |
author_facet | Umadevi, M. Raju, Potharaju Yamuna, R. Mohanakrishnan, Arasambattu K. Chakkaravarthi, G. |
author_sort | Umadevi, M. |
collection | PubMed |
description | In the title compound, C(23)H(23)NO(6)S, the phenyl ring is perpendicular [dihedral angle = 89.34 (9)°] to the indole ring system. In the molecule, the ethoxy groups are each disordered over two sets of sites with occupancy ratios of 0.671 (6):0.329 (6) and 0.75 (3):0.25 (3). The molecular conformation is consolidated by a weak C—H⋯O interaction, which generates an S(6) graph–set motif. The packing of the molecules in the crystal structure features weak C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-4719962 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-47199622016-02-11 Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate Umadevi, M. Raju, Potharaju Yamuna, R. Mohanakrishnan, Arasambattu K. Chakkaravarthi, G. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(23)H(23)NO(6)S, the phenyl ring is perpendicular [dihedral angle = 89.34 (9)°] to the indole ring system. In the molecule, the ethoxy groups are each disordered over two sets of sites with occupancy ratios of 0.671 (6):0.329 (6) and 0.75 (3):0.25 (3). The molecular conformation is consolidated by a weak C—H⋯O interaction, which generates an S(6) graph–set motif. The packing of the molecules in the crystal structure features weak C—H⋯π interactions. International Union of Crystallography 2015-12-09 /pmc/articles/PMC4719962/ /pubmed/26870481 http://dx.doi.org/10.1107/S2056989015023075 Text en © Umadevi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Umadevi, M. Raju, Potharaju Yamuna, R. Mohanakrishnan, Arasambattu K. Chakkaravarthi, G. Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
title | Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
title_full | Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
title_fullStr | Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
title_full_unstemmed | Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
title_short | Crystal structure of (E)-diethyl 2-[(1-phenylsulfonyl-1H-indol-3-yl)methylidene]succinate |
title_sort | crystal structure of (e)-diethyl 2-[(1-phenylsulfonyl-1h-indol-3-yl)methylidene]succinate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719962/ https://www.ncbi.nlm.nih.gov/pubmed/26870481 http://dx.doi.org/10.1107/S2056989015023075 |
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