Crystal structure of (1Z,2E)-cinnamaldehyde oxime

The title compound, C(9)H(9)NO, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. The conformation of the two mol­ecules differs slightly with the phenyl ring in mol­ecule A, forming a dihedral angle of 15.38 (12)° with the oxime group (O—N=C), compared to the correspond...

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Detalles Bibliográficos
Autores principales: Bugenhagen, Bernhard, Al Soom, Nuha, Al Jasem, Yosef, Thiemann, Thies
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719980/
https://www.ncbi.nlm.nih.gov/pubmed/26870499
http://dx.doi.org/10.1107/S2056989015023853
Descripción
Sumario:The title compound, C(9)H(9)NO, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. The conformation of the two mol­ecules differs slightly with the phenyl ring in mol­ecule A, forming a dihedral angle of 15.38 (12)° with the oxime group (O—N=C), compared to the corresponding angle of 26.29 (11)° in mol­ecule B. In the crystal, the A and B mol­ecules are linked head-to-head by O—H⋯N hydrogen bonds, forming –A–B–A–B– zigzag chains along [010]. Within the chains and between neighbouring chains there are C—H⋯π inter­actions present, forming a three-dimensional structure.

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