Crystal structure of 3-bromo-9-ethyl-9H-carbazole

In the title compound, C(14)H(12)BrN, the tricyclic ring system is essentially planar (r.m.s. deviation 0.026 Å). The carbon atoms of the ethyl group deviate from the mean plane by 0.148 (9) (CH(2)) and 1.59 (1) Å (CH(3)). In the crystal, H⋯π contacts [2.698–2.898 Å] shorter than the van der Waals c...

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Detalles Bibliográficos
Autores principales: Bezuglyi, Mykola, Grybauskaite, Gintare, Bagdziunas, Gintautas, Grazulevicius, Juozas Vidas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719982/
https://www.ncbi.nlm.nih.gov/pubmed/26870501
http://dx.doi.org/10.1107/S2056989015023907
Descripción
Sumario:In the title compound, C(14)H(12)BrN, the tricyclic ring system is essentially planar (r.m.s. deviation 0.026 Å). The carbon atoms of the ethyl group deviate from the mean plane by 0.148 (9) (CH(2)) and 1.59 (1) Å (CH(3)). In the crystal, H⋯π contacts [2.698–2.898 Å] shorter than the van der Waals contact distance of 3.70 Å are observed. A scalable to gram quantities selective synthesis of mono-bromine-substituted carbazole derivatives was developed.

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