Crystal structure of 3-bromo-9-ethyl-9H-carbazole

In the title compound, C(14)H(12)BrN, the tricyclic ring system is essentially planar (r.m.s. deviation 0.026 Å). The carbon atoms of the ethyl group deviate from the mean plane by 0.148 (9) (CH(2)) and 1.59 (1) Å (CH(3)). In the crystal, H⋯π contacts [2.698–2.898 Å] shorter than the van der Waals c...

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Detalles Bibliográficos
Autores principales: Bezuglyi, Mykola, Grybauskaite, Gintare, Bagdziunas, Gintautas, Grazulevicius, Juozas Vidas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719982/
https://www.ncbi.nlm.nih.gov/pubmed/26870501
http://dx.doi.org/10.1107/S2056989015023907
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author Bezuglyi, Mykola
Grybauskaite, Gintare
Bagdziunas, Gintautas
Grazulevicius, Juozas Vidas
author_facet Bezuglyi, Mykola
Grybauskaite, Gintare
Bagdziunas, Gintautas
Grazulevicius, Juozas Vidas
author_sort Bezuglyi, Mykola
collection PubMed
description In the title compound, C(14)H(12)BrN, the tricyclic ring system is essentially planar (r.m.s. deviation 0.026 Å). The carbon atoms of the ethyl group deviate from the mean plane by 0.148 (9) (CH(2)) and 1.59 (1) Å (CH(3)). In the crystal, H⋯π contacts [2.698–2.898 Å] shorter than the van der Waals contact distance of 3.70 Å are observed. A scalable to gram quantities selective synthesis of mono-bromine-substituted carbazole derivatives was developed.
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spelling pubmed-47199822016-02-11 Crystal structure of 3-bromo-9-ethyl-9H-carbazole Bezuglyi, Mykola Grybauskaite, Gintare Bagdziunas, Gintautas Grazulevicius, Juozas Vidas Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(14)H(12)BrN, the tricyclic ring system is essentially planar (r.m.s. deviation 0.026 Å). The carbon atoms of the ethyl group deviate from the mean plane by 0.148 (9) (CH(2)) and 1.59 (1) Å (CH(3)). In the crystal, H⋯π contacts [2.698–2.898 Å] shorter than the van der Waals contact distance of 3.70 Å are observed. A scalable to gram quantities selective synthesis of mono-bromine-substituted carbazole derivatives was developed. International Union of Crystallography 2015-12-19 /pmc/articles/PMC4719982/ /pubmed/26870501 http://dx.doi.org/10.1107/S2056989015023907 Text en © Bezuglyi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Bezuglyi, Mykola
Grybauskaite, Gintare
Bagdziunas, Gintautas
Grazulevicius, Juozas Vidas
Crystal structure of 3-bromo-9-ethyl-9H-carbazole
title Crystal structure of 3-bromo-9-ethyl-9H-carbazole
title_full Crystal structure of 3-bromo-9-ethyl-9H-carbazole
title_fullStr Crystal structure of 3-bromo-9-ethyl-9H-carbazole
title_full_unstemmed Crystal structure of 3-bromo-9-ethyl-9H-carbazole
title_short Crystal structure of 3-bromo-9-ethyl-9H-carbazole
title_sort crystal structure of 3-bromo-9-ethyl-9h-carbazole
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719982/
https://www.ncbi.nlm.nih.gov/pubmed/26870501
http://dx.doi.org/10.1107/S2056989015023907
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