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Crystal structure of methyl (2Z)-2-{[N-(2-formyl­phen­yl)-4-methyl­benzene­sulfonamido]­meth­yl}-3-(4-meth­oxy­phen­yl)prop-2-enoate

In the title compound, C(26)H(25)NO(6)S, the S atom shows a distorted tetra­hedral geometry, with O—S—O [119.46 (9)°] and N—S—C [107.16 (7)°] angles deviating from ideal tetra­hedral values, a fact attributed to the Thorpe–Ingold effect. The sulfonyl-bound phenyl ring forms dihedral angles of 41.1 (...

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Detalles Bibliográficos
Autores principales: Trigunait, Ankur, Damodharan, Kannan, Manickam, Bakthadoss, Krishnasamy, Gunasekaran
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719993/
https://www.ncbi.nlm.nih.gov/pubmed/26870512
http://dx.doi.org/10.1107/S2056989015024172
Descripción
Sumario:In the title compound, C(26)H(25)NO(6)S, the S atom shows a distorted tetra­hedral geometry, with O—S—O [119.46 (9)°] and N—S—C [107.16 (7)°] angles deviating from ideal tetra­hedral values, a fact attributed to the Thorpe–Ingold effect. The sulfonyl-bound phenyl ring forms dihedral angles of 41.1 (1) and 83.3 (1)°, respectively, with the formyl­phenyl and phenyl rings. The dihedral angle between formyl­phenyl and phenyl rings is 47.6 (1)°. The crystal packing features C—H⋯O hydrogen-bond inter­actions.