Crystal structure of methyl (2Z)-2-{[N-(2-formyl­phen­yl)-4-methyl­benzene­sulfonamido]­meth­yl}-3-(4-meth­oxy­phen­yl)prop-2-enoate

In the title compound, C(26)H(25)NO(6)S, the S atom shows a distorted tetra­hedral geometry, with O—S—O [119.46 (9)°] and N—S—C [107.16 (7)°] angles deviating from ideal tetra­hedral values, a fact attributed to the Thorpe–Ingold effect. The sulfonyl-bound phenyl ring forms dihedral angles of 41.1 (...

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Autores principales: Trigunait, Ankur, Damodharan, Kannan, Manickam, Bakthadoss, Krishnasamy, Gunasekaran
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719993/
https://www.ncbi.nlm.nih.gov/pubmed/26870512
http://dx.doi.org/10.1107/S2056989015024172
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author Trigunait, Ankur
Damodharan, Kannan
Manickam, Bakthadoss
Krishnasamy, Gunasekaran
author_facet Trigunait, Ankur
Damodharan, Kannan
Manickam, Bakthadoss
Krishnasamy, Gunasekaran
author_sort Trigunait, Ankur
collection PubMed
description In the title compound, C(26)H(25)NO(6)S, the S atom shows a distorted tetra­hedral geometry, with O—S—O [119.46 (9)°] and N—S—C [107.16 (7)°] angles deviating from ideal tetra­hedral values, a fact attributed to the Thorpe–Ingold effect. The sulfonyl-bound phenyl ring forms dihedral angles of 41.1 (1) and 83.3 (1)°, respectively, with the formyl­phenyl and phenyl rings. The dihedral angle between formyl­phenyl and phenyl rings is 47.6 (1)°. The crystal packing features C—H⋯O hydrogen-bond inter­actions.
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spelling pubmed-47199932016-02-11 Crystal structure of methyl (2Z)-2-{[N-(2-formyl­phen­yl)-4-methyl­benzene­sulfonamido]­meth­yl}-3-(4-meth­oxy­phen­yl)prop-2-enoate Trigunait, Ankur Damodharan, Kannan Manickam, Bakthadoss Krishnasamy, Gunasekaran Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(26)H(25)NO(6)S, the S atom shows a distorted tetra­hedral geometry, with O—S—O [119.46 (9)°] and N—S—C [107.16 (7)°] angles deviating from ideal tetra­hedral values, a fact attributed to the Thorpe–Ingold effect. The sulfonyl-bound phenyl ring forms dihedral angles of 41.1 (1) and 83.3 (1)°, respectively, with the formyl­phenyl and phenyl rings. The dihedral angle between formyl­phenyl and phenyl rings is 47.6 (1)°. The crystal packing features C—H⋯O hydrogen-bond inter­actions. International Union of Crystallography 2015-12-31 /pmc/articles/PMC4719993/ /pubmed/26870512 http://dx.doi.org/10.1107/S2056989015024172 Text en © Trigunait et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Trigunait, Ankur
Damodharan, Kannan
Manickam, Bakthadoss
Krishnasamy, Gunasekaran
Crystal structure of methyl (2Z)-2-{[N-(2-formyl­phen­yl)-4-methyl­benzene­sulfonamido]­meth­yl}-3-(4-meth­oxy­phen­yl)prop-2-enoate
title Crystal structure of methyl (2Z)-2-{[N-(2-formyl­phen­yl)-4-methyl­benzene­sulfonamido]­meth­yl}-3-(4-meth­oxy­phen­yl)prop-2-enoate
title_full Crystal structure of methyl (2Z)-2-{[N-(2-formyl­phen­yl)-4-methyl­benzene­sulfonamido]­meth­yl}-3-(4-meth­oxy­phen­yl)prop-2-enoate
title_fullStr Crystal structure of methyl (2Z)-2-{[N-(2-formyl­phen­yl)-4-methyl­benzene­sulfonamido]­meth­yl}-3-(4-meth­oxy­phen­yl)prop-2-enoate
title_full_unstemmed Crystal structure of methyl (2Z)-2-{[N-(2-formyl­phen­yl)-4-methyl­benzene­sulfonamido]­meth­yl}-3-(4-meth­oxy­phen­yl)prop-2-enoate
title_short Crystal structure of methyl (2Z)-2-{[N-(2-formyl­phen­yl)-4-methyl­benzene­sulfonamido]­meth­yl}-3-(4-meth­oxy­phen­yl)prop-2-enoate
title_sort crystal structure of methyl (2z)-2-{[n-(2-formyl­phen­yl)-4-methyl­benzene­sulfonamido]­meth­yl}-3-(4-meth­oxy­phen­yl)prop-2-enoate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719993/
https://www.ncbi.nlm.nih.gov/pubmed/26870512
http://dx.doi.org/10.1107/S2056989015024172
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