Crystal structure of 15-(2-chloro­phen­yl)-6b-hy­droxy-17-methyl-6b,7,16,17-tetra­hydro-7,14a-methanona­phtho[1′,8′:1,2,3]pyrrolo­[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one

In the title compound, C(34)H(25)ClN(2)O(2), the fused pyrrolidine ring adopts an envelope conformation with the N atom as the flap. The two adjacent cyclo­pentane rings also adopt envelope conformations. The mean plane of the pyrrolidine ring makes dihedral angles of 40.53 (10) and 80.23 (10)° with...

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Autores principales: Joseph, J. M., Viswanathan, Vijayan, Velmurugan, Devadasan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719995/
https://www.ncbi.nlm.nih.gov/pubmed/26870514
http://dx.doi.org/10.1107/S2056989015024767
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author Joseph, J. M.
Viswanathan, Vijayan
Velmurugan, Devadasan
author_facet Joseph, J. M.
Viswanathan, Vijayan
Velmurugan, Devadasan
author_sort Joseph, J. M.
collection PubMed
description In the title compound, C(34)H(25)ClN(2)O(2), the fused pyrrolidine ring adopts an envelope conformation with the N atom as the flap. The two adjacent cyclo­pentane rings also adopt envelope conformations. The mean plane of the pyrrolidine ring makes dihedral angles of 40.53 (10) and 80.23 (10)° with the mean planes of the cyclo­pentane rings. The dihedral angle between the mean planes of the cyclo­pentane rings is 46.71 (9)°. An intra­molecular O—H⋯N hydrogen bond is observed. In the crystal, mol­ecules are linked by C—H⋯O, C—H⋯N and C—H⋯π inter­actions, forming a layer parallel to (10-2).
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spelling pubmed-47199952016-02-11 Crystal structure of 15-(2-chloro­phen­yl)-6b-hy­droxy-17-methyl-6b,7,16,17-tetra­hydro-7,14a-methanona­phtho[1′,8′:1,2,3]pyrrolo­[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one Joseph, J. M. Viswanathan, Vijayan Velmurugan, Devadasan Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(34)H(25)ClN(2)O(2), the fused pyrrolidine ring adopts an envelope conformation with the N atom as the flap. The two adjacent cyclo­pentane rings also adopt envelope conformations. The mean plane of the pyrrolidine ring makes dihedral angles of 40.53 (10) and 80.23 (10)° with the mean planes of the cyclo­pentane rings. The dihedral angle between the mean planes of the cyclo­pentane rings is 46.71 (9)°. An intra­molecular O—H⋯N hydrogen bond is observed. In the crystal, mol­ecules are linked by C—H⋯O, C—H⋯N and C—H⋯π inter­actions, forming a layer parallel to (10-2). International Union of Crystallography 2015-12-31 /pmc/articles/PMC4719995/ /pubmed/26870514 http://dx.doi.org/10.1107/S2056989015024767 Text en © Joseph et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Joseph, J. M.
Viswanathan, Vijayan
Velmurugan, Devadasan
Crystal structure of 15-(2-chloro­phen­yl)-6b-hy­droxy-17-methyl-6b,7,16,17-tetra­hydro-7,14a-methanona­phtho[1′,8′:1,2,3]pyrrolo­[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one
title Crystal structure of 15-(2-chloro­phen­yl)-6b-hy­droxy-17-methyl-6b,7,16,17-tetra­hydro-7,14a-methanona­phtho[1′,8′:1,2,3]pyrrolo­[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one
title_full Crystal structure of 15-(2-chloro­phen­yl)-6b-hy­droxy-17-methyl-6b,7,16,17-tetra­hydro-7,14a-methanona­phtho[1′,8′:1,2,3]pyrrolo­[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one
title_fullStr Crystal structure of 15-(2-chloro­phen­yl)-6b-hy­droxy-17-methyl-6b,7,16,17-tetra­hydro-7,14a-methanona­phtho[1′,8′:1,2,3]pyrrolo­[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one
title_full_unstemmed Crystal structure of 15-(2-chloro­phen­yl)-6b-hy­droxy-17-methyl-6b,7,16,17-tetra­hydro-7,14a-methanona­phtho[1′,8′:1,2,3]pyrrolo­[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one
title_short Crystal structure of 15-(2-chloro­phen­yl)-6b-hy­droxy-17-methyl-6b,7,16,17-tetra­hydro-7,14a-methanona­phtho[1′,8′:1,2,3]pyrrolo­[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15H)-one
title_sort crystal structure of 15-(2-chloro­phen­yl)-6b-hy­droxy-17-methyl-6b,7,16,17-tetra­hydro-7,14a-methanona­phtho[1′,8′:1,2,3]pyrrolo­[3′,2′:8,8a]azuleno[5,6-b]quinolin-14(15h)-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719995/
https://www.ncbi.nlm.nih.gov/pubmed/26870514
http://dx.doi.org/10.1107/S2056989015024767
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