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Synthesis and reactivity of aliphatic sulfur pentafluorides from substituted (pentafluorosulfanyl)benzenes
Oxidation of 3- and 4-pentafluorosulfanyl-substituted anisoles and phenols with hydrogen peroxide and sulfuric acid provided a mixture of SF(5)-substituted muconolactone, maleic, and succinic acids. A plausible mechanism for the formation of the aliphatic SF(5) compounds was presented and their chem...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4734437/ https://www.ncbi.nlm.nih.gov/pubmed/26877813 http://dx.doi.org/10.3762/bjoc.12.12 |