Generation of a Dynamic System of Three‐Dimensional Tetrahedral Polycatenanes

Seven of the best: A dynamic combinatorial library of polycatenated tetrahedra was prepared by complexation between a dynamic Fe(4)L(6) tetrahedral cage, constructed from ligands containing an electron‐deficient naphthalenediimide core, and an electron‐rich aromatic crown ether, 1,5‐dinaphtho[38]cro...

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Detalles Bibliográficos
Autores principales: Black, Samuel P., Stefankiewicz, Artur R., Smulders, Maarten M. J., Sattler, Dominik, Schalley, Christoph A., Nitschke, Jonathan R., Sanders, Jeremy K. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY‐VCH Verlag 2013
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4736444/
https://www.ncbi.nlm.nih.gov/pubmed/23606312
http://dx.doi.org/10.1002/anie.201209708
Descripción
Sumario:Seven of the best: A dynamic combinatorial library of polycatenated tetrahedra was prepared by complexation between a dynamic Fe(4)L(6) tetrahedral cage, constructed from ligands containing an electron‐deficient naphthalenediimide core, and an electron‐rich aromatic crown ether, 1,5‐dinaphtho[38]crown‐10. The highest order species in the library is the tetrahedral [7]catenane.[Image: see text]

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