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Nucleophilic arylation with tetraarylphosphonium salts
Organic phosphonium salts have served as important intermediates in synthetic chemistry. But the use of a substituent on the positive phosphorus as a nucleophile to construct C–C bond remains a significant challenge. Here we report an efficient transition-metal-free protocol for the direct nucleophi...
Autores principales: | Deng, Zuyong, Lin, Jin-Hong, Xiao, Ji-Chang |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4740112/ https://www.ncbi.nlm.nih.gov/pubmed/26822205 http://dx.doi.org/10.1038/ncomms10337 |
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