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Mechanistic Studies of ε-Caprolactone Polymerization by (salen)AlOR Complexes and a Predictive Model for Cyclic Ester Polymerizations

[Image: see text] Aluminum alkoxide complexes (2) of salen ligands with a three-carbon linker and para substituents having variable electron-withdrawing capabilities (X = NO(2), Br, OMe) were prepared, and the kinetics of their ring-opening polymerization (ROP) of ε-caprolactone (CL) were investigat...

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Detalles Bibliográficos
Autores principales:	Marlier, Elodie E., Macaranas, Joahanna A., Marell, Daniel J., Dunbar, Christine R., Johnson, Michelle A., DePorre, Yvonne, Miranda, Maria O., Neisen, Benjamin D., Cramer, Christopher J., Hillmyer, Marc A., Tolman, William B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2016
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4749094/ https://www.ncbi.nlm.nih.gov/pubmed/26900488 http://dx.doi.org/10.1021/acscatal.5b02607

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