Identification of the dominant photochemical pathways and mechanistic insights to the ultrafast ligand exchange of Fe(CO)(5) to Fe(CO)(4)EtOH

We utilized femtosecond time-resolved resonant inelastic X-ray scattering and ab initio theory to study the transient electronic structure and the photoinduced molecular dynamics of a model metal carbonyl photocatalyst Fe(CO)(5) in ethanol solution. We propose mechanistic explanation for the paralle...

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Detalles Bibliográficos
Autores principales: Kunnus, K., Josefsson, I., Rajkovic, I., Schreck, S., Quevedo, W., Beye, M., Weniger, C., Grübel, S., Scholz, M., Nordlund, D., Zhang, W., Hartsock, R. W., Gaffney, K. J., Schlotter, W. F., Turner, J. J., Kennedy, B., Hennies, F., de Groot, F. M. F., Techert, S., Odelius, M., Wernet, Ph., Föhlisch, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Crystallographic Association 2016
Materias:
SPECIAL TOPIC: THE HAMBURG CONFERENCE ON FEMTOCHEMISTRY (FEMTO12)
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4752567/
https://www.ncbi.nlm.nih.gov/pubmed/26958587
http://dx.doi.org/10.1063/1.4941602

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