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Holey graphene frameworks for highly selective post-combustion carbon capture

Atmospheric CO(2) concentrations continue to rise rapidly in response to increased combustion of fossil fuels, contributing to global climate change. In order to mitigate the effects of global warming, development of new materials for cost-effective and energy-efficient CO(2) capture is critically i...

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Autores principales: Chowdhury, Shamik, Balasubramanian, Rajasekhar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4754909/
https://www.ncbi.nlm.nih.gov/pubmed/26879393
http://dx.doi.org/10.1038/srep21537
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author Chowdhury, Shamik
Balasubramanian, Rajasekhar
author_facet Chowdhury, Shamik
Balasubramanian, Rajasekhar
author_sort Chowdhury, Shamik
collection PubMed
description Atmospheric CO(2) concentrations continue to rise rapidly in response to increased combustion of fossil fuels, contributing to global climate change. In order to mitigate the effects of global warming, development of new materials for cost-effective and energy-efficient CO(2) capture is critically important. Graphene-based porous materials are an emerging class of solid adsorbents for selectively removing CO(2) from flue gases. Herein, we report a simple and scalable approach to produce three-dimensional holey graphene frameworks with tunable porosity and pore geometry, and demonstrate their application as high-performance CO(2) adsorbents. These holey graphene macrostructures exhibit a significantly improved specific surface area and pore volume compared to their pristine counterparts, and can be effectively used in post-combustion CO(2) adsorption systems because of their intrinsic hydrophobicity together with good gravimetric storage capacities, rapid removal capabilities, superior cycling stabilities, and moderate initial isosteric heats. In addition, an exceptionally high CO(2) over N(2) selectivity can be achieved under conditions relevant to capture from the dry exhaust gas stream of a coal burning power plant, suggesting the possibility of recovering highly pure CO(2) for long-term sequestration and/or utilization for downstream applications.
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spelling pubmed-47549092016-02-24 Holey graphene frameworks for highly selective post-combustion carbon capture Chowdhury, Shamik Balasubramanian, Rajasekhar Sci Rep Article Atmospheric CO(2) concentrations continue to rise rapidly in response to increased combustion of fossil fuels, contributing to global climate change. In order to mitigate the effects of global warming, development of new materials for cost-effective and energy-efficient CO(2) capture is critically important. Graphene-based porous materials are an emerging class of solid adsorbents for selectively removing CO(2) from flue gases. Herein, we report a simple and scalable approach to produce three-dimensional holey graphene frameworks with tunable porosity and pore geometry, and demonstrate their application as high-performance CO(2) adsorbents. These holey graphene macrostructures exhibit a significantly improved specific surface area and pore volume compared to their pristine counterparts, and can be effectively used in post-combustion CO(2) adsorption systems because of their intrinsic hydrophobicity together with good gravimetric storage capacities, rapid removal capabilities, superior cycling stabilities, and moderate initial isosteric heats. In addition, an exceptionally high CO(2) over N(2) selectivity can be achieved under conditions relevant to capture from the dry exhaust gas stream of a coal burning power plant, suggesting the possibility of recovering highly pure CO(2) for long-term sequestration and/or utilization for downstream applications. Nature Publishing Group 2016-02-16 /pmc/articles/PMC4754909/ /pubmed/26879393 http://dx.doi.org/10.1038/srep21537 Text en Copyright © 2016, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Chowdhury, Shamik
Balasubramanian, Rajasekhar
Holey graphene frameworks for highly selective post-combustion carbon capture
title Holey graphene frameworks for highly selective post-combustion carbon capture
title_full Holey graphene frameworks for highly selective post-combustion carbon capture
title_fullStr Holey graphene frameworks for highly selective post-combustion carbon capture
title_full_unstemmed Holey graphene frameworks for highly selective post-combustion carbon capture
title_short Holey graphene frameworks for highly selective post-combustion carbon capture
title_sort holey graphene frameworks for highly selective post-combustion carbon capture
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4754909/
https://www.ncbi.nlm.nih.gov/pubmed/26879393
http://dx.doi.org/10.1038/srep21537
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