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An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance

The absorption ability and photocatalytic activity of photocatalytic materials play important roles in improving the pollutants removal effects. Herein, we reported a new kind of photocatalytic material, which was synthesized by simultaneously designing hierarchical porous magnesian (PM) substrate a...

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Detalles Bibliográficos
Autores principales: Yang, Lu, Wang, Fazhou, Shu, Chang, Liu, Peng, Zhang, Wenqin, Hu, Shuguang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4756697/
https://www.ncbi.nlm.nih.gov/pubmed/26883972
http://dx.doi.org/10.1038/srep21617
Descripción
Sumario:The absorption ability and photocatalytic activity of photocatalytic materials play important roles in improving the pollutants removal effects. Herein, we reported a new kind of photocatalytic material, which was synthesized by simultaneously designing hierarchical porous magnesian (PM) substrate and TiO(2) catalyst modification. Particularly, PM substrate could be facilely prepared by controlling its crystal phase (Phase 5, Mg(3)Cl(OH)(5)·4H(2)O), while Ag/AgCl particles modification of TiO(2) could be achieved by in situ ion exchange between Ag(+) and above crystal Phase. Physiochemical analysis shows that Ag/AgCl/TiO(2)/PM material has higher visible and ultraviolet light absorption response, and excellent gas absorption performance compared to other controls. These suggested that Ag/AgCl/TiO(2)/PM material could produce more efficient photocatalytic effects. Its photocatalytic reaction rate was 5.21 and 30.57 times higher than that of TiO(2)/PM and TiO(2)/imporous magnesian substrate, respectively. Thus, this material and its intergration synthesis method could provide a novel strategy for high-efficiency application and modification of TiO(2) photocatalyst in engineering filed.