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An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance
The absorption ability and photocatalytic activity of photocatalytic materials play important roles in improving the pollutants removal effects. Herein, we reported a new kind of photocatalytic material, which was synthesized by simultaneously designing hierarchical porous magnesian (PM) substrate a...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4756697/ https://www.ncbi.nlm.nih.gov/pubmed/26883972 http://dx.doi.org/10.1038/srep21617 |
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author | Yang, Lu Wang, Fazhou Shu, Chang Liu, Peng Zhang, Wenqin Hu, Shuguang |
author_facet | Yang, Lu Wang, Fazhou Shu, Chang Liu, Peng Zhang, Wenqin Hu, Shuguang |
author_sort | Yang, Lu |
collection | PubMed |
description | The absorption ability and photocatalytic activity of photocatalytic materials play important roles in improving the pollutants removal effects. Herein, we reported a new kind of photocatalytic material, which was synthesized by simultaneously designing hierarchical porous magnesian (PM) substrate and TiO(2) catalyst modification. Particularly, PM substrate could be facilely prepared by controlling its crystal phase (Phase 5, Mg(3)Cl(OH)(5)·4H(2)O), while Ag/AgCl particles modification of TiO(2) could be achieved by in situ ion exchange between Ag(+) and above crystal Phase. Physiochemical analysis shows that Ag/AgCl/TiO(2)/PM material has higher visible and ultraviolet light absorption response, and excellent gas absorption performance compared to other controls. These suggested that Ag/AgCl/TiO(2)/PM material could produce more efficient photocatalytic effects. Its photocatalytic reaction rate was 5.21 and 30.57 times higher than that of TiO(2)/PM and TiO(2)/imporous magnesian substrate, respectively. Thus, this material and its intergration synthesis method could provide a novel strategy for high-efficiency application and modification of TiO(2) photocatalyst in engineering filed. |
format | Online Article Text |
id | pubmed-4756697 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | Nature Publishing Group |
record_format | MEDLINE/PubMed |
spelling | pubmed-47566972016-02-25 An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance Yang, Lu Wang, Fazhou Shu, Chang Liu, Peng Zhang, Wenqin Hu, Shuguang Sci Rep Article The absorption ability and photocatalytic activity of photocatalytic materials play important roles in improving the pollutants removal effects. Herein, we reported a new kind of photocatalytic material, which was synthesized by simultaneously designing hierarchical porous magnesian (PM) substrate and TiO(2) catalyst modification. Particularly, PM substrate could be facilely prepared by controlling its crystal phase (Phase 5, Mg(3)Cl(OH)(5)·4H(2)O), while Ag/AgCl particles modification of TiO(2) could be achieved by in situ ion exchange between Ag(+) and above crystal Phase. Physiochemical analysis shows that Ag/AgCl/TiO(2)/PM material has higher visible and ultraviolet light absorption response, and excellent gas absorption performance compared to other controls. These suggested that Ag/AgCl/TiO(2)/PM material could produce more efficient photocatalytic effects. Its photocatalytic reaction rate was 5.21 and 30.57 times higher than that of TiO(2)/PM and TiO(2)/imporous magnesian substrate, respectively. Thus, this material and its intergration synthesis method could provide a novel strategy for high-efficiency application and modification of TiO(2) photocatalyst in engineering filed. Nature Publishing Group 2016-02-17 /pmc/articles/PMC4756697/ /pubmed/26883972 http://dx.doi.org/10.1038/srep21617 Text en Copyright © 2016, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Article Yang, Lu Wang, Fazhou Shu, Chang Liu, Peng Zhang, Wenqin Hu, Shuguang An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance |
title | An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance |
title_full | An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance |
title_fullStr | An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance |
title_full_unstemmed | An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance |
title_short | An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance |
title_sort | in-situ synthesis of ag/agcl/tio(2)/hierarchical porous magnesian material and its photocatalytic performance |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4756697/ https://www.ncbi.nlm.nih.gov/pubmed/26883972 http://dx.doi.org/10.1038/srep21617 |
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