Cargando…

An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance

The absorption ability and photocatalytic activity of photocatalytic materials play important roles in improving the pollutants removal effects. Herein, we reported a new kind of photocatalytic material, which was synthesized by simultaneously designing hierarchical porous magnesian (PM) substrate a...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Lu, Wang, Fazhou, Shu, Chang, Liu, Peng, Zhang, Wenqin, Hu, Shuguang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4756697/
https://www.ncbi.nlm.nih.gov/pubmed/26883972
http://dx.doi.org/10.1038/srep21617
_version_ 1782416377859014656
author Yang, Lu
Wang, Fazhou
Shu, Chang
Liu, Peng
Zhang, Wenqin
Hu, Shuguang
author_facet Yang, Lu
Wang, Fazhou
Shu, Chang
Liu, Peng
Zhang, Wenqin
Hu, Shuguang
author_sort Yang, Lu
collection PubMed
description The absorption ability and photocatalytic activity of photocatalytic materials play important roles in improving the pollutants removal effects. Herein, we reported a new kind of photocatalytic material, which was synthesized by simultaneously designing hierarchical porous magnesian (PM) substrate and TiO(2) catalyst modification. Particularly, PM substrate could be facilely prepared by controlling its crystal phase (Phase 5, Mg(3)Cl(OH)(5)·4H(2)O), while Ag/AgCl particles modification of TiO(2) could be achieved by in situ ion exchange between Ag(+) and above crystal Phase. Physiochemical analysis shows that Ag/AgCl/TiO(2)/PM material has higher visible and ultraviolet light absorption response, and excellent gas absorption performance compared to other controls. These suggested that Ag/AgCl/TiO(2)/PM material could produce more efficient photocatalytic effects. Its photocatalytic reaction rate was 5.21 and 30.57 times higher than that of TiO(2)/PM and TiO(2)/imporous magnesian substrate, respectively. Thus, this material and its intergration synthesis method could provide a novel strategy for high-efficiency application and modification of TiO(2) photocatalyst in engineering filed.
format Online
Article
Text
id pubmed-4756697
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher Nature Publishing Group
record_format MEDLINE/PubMed
spelling pubmed-47566972016-02-25 An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance Yang, Lu Wang, Fazhou Shu, Chang Liu, Peng Zhang, Wenqin Hu, Shuguang Sci Rep Article The absorption ability and photocatalytic activity of photocatalytic materials play important roles in improving the pollutants removal effects. Herein, we reported a new kind of photocatalytic material, which was synthesized by simultaneously designing hierarchical porous magnesian (PM) substrate and TiO(2) catalyst modification. Particularly, PM substrate could be facilely prepared by controlling its crystal phase (Phase 5, Mg(3)Cl(OH)(5)·4H(2)O), while Ag/AgCl particles modification of TiO(2) could be achieved by in situ ion exchange between Ag(+) and above crystal Phase. Physiochemical analysis shows that Ag/AgCl/TiO(2)/PM material has higher visible and ultraviolet light absorption response, and excellent gas absorption performance compared to other controls. These suggested that Ag/AgCl/TiO(2)/PM material could produce more efficient photocatalytic effects. Its photocatalytic reaction rate was 5.21 and 30.57 times higher than that of TiO(2)/PM and TiO(2)/imporous magnesian substrate, respectively. Thus, this material and its intergration synthesis method could provide a novel strategy for high-efficiency application and modification of TiO(2) photocatalyst in engineering filed. Nature Publishing Group 2016-02-17 /pmc/articles/PMC4756697/ /pubmed/26883972 http://dx.doi.org/10.1038/srep21617 Text en Copyright © 2016, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Yang, Lu
Wang, Fazhou
Shu, Chang
Liu, Peng
Zhang, Wenqin
Hu, Shuguang
An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance
title An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance
title_full An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance
title_fullStr An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance
title_full_unstemmed An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance
title_short An in-situ synthesis of Ag/AgCl/TiO(2)/hierarchical porous magnesian material and its photocatalytic performance
title_sort in-situ synthesis of ag/agcl/tio(2)/hierarchical porous magnesian material and its photocatalytic performance
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4756697/
https://www.ncbi.nlm.nih.gov/pubmed/26883972
http://dx.doi.org/10.1038/srep21617
work_keys_str_mv AT yanglu aninsitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT wangfazhou aninsitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT shuchang aninsitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT liupeng aninsitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT zhangwenqin aninsitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT hushuguang aninsitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT yanglu insitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT wangfazhou insitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT shuchang insitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT liupeng insitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT zhangwenqin insitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance
AT hushuguang insitusynthesisofagagcltio2hierarchicalporousmagnesianmaterialanditsphotocatalyticperformance