Cargando…
Rh(iii)-catalyzed diastereoselective C–H bond addition/cyclization cascade of enone tethered aldehydes
The Rh(iii)-catalyzed cascade addition of a C–H bond across alkene and carbonyl π-bonds is reported. The reaction proceeds under mild reaction conditions with low catalyst loading. A range of directing groups were shown to be effective as was the functionalization of alkenyl in addition to aromatic...
Autores principales: | Boerth, Jeffrey A., Ellman, Jonathan A. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4762265/ https://www.ncbi.nlm.nih.gov/pubmed/26918112 http://dx.doi.org/10.1039/c5sc04138d |
Ejemplares similares
-
Selective and synergistic cobalt(III)-catalyzed three-component C–H bond addition to dienes and aldehydes
por: Boerth, Jeffrey A., et al.
Publicado: (2018) -
Cobalt(III)-Catalyzed
Synthesis of Indazoles and Furans
by C–H Bond Functionalization/Addition/Cyclization Cascades
por: Hummel, Joshua R., et al.
Publicado: (2014) -
Enantioselective Cu(I)-catalyzed borylative cyclization of enone-tethered cyclohexadienones and mechanistic insights
por: Jadhav, Sandip B., et al.
Publicado: (2022) -
Gold(i)-catalyzed stereoselective cyclization of 1,3-enyne aldehydes by a 1,3-acyloxy migration/Nazarov cyclization/aldol addition cascade
por: Brandstätter, Marco, et al.
Publicado: (2019) -
Asymmetric
Synthesis of α-Branched Amines
via Rh(III)-Catalyzed C–H Bond Functionalization
por: Wangweerawong, Apiwat, et al.
Publicado: (2014)