Intramolecular interactions in the polar headgroup of sphingosine: serinol

The intramolecular interactions in the lipid sphingosine have been elucidated through the investigation of the amino alcohol serinol which mimics its polar headgroup. Intricate networks of intramolecular hydrogen bonds involving the hydroxyl groups and the amino group contribute to the stabilisation...

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Detalles Bibliográficos
Autores principales: Loru, Donatella, Peña, Isabel, Alonso, José L., Eugenia Sanz, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4766959/
https://www.ncbi.nlm.nih.gov/pubmed/26727395
http://dx.doi.org/10.1039/c5cc09423b
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author Loru, Donatella
Peña, Isabel
Alonso, José L.
Eugenia Sanz, M.
author_facet Loru, Donatella
Peña, Isabel
Alonso, José L.
Eugenia Sanz, M.
author_sort Loru, Donatella
collection PubMed
description The intramolecular interactions in the lipid sphingosine have been elucidated through the investigation of the amino alcohol serinol which mimics its polar headgroup. Intricate networks of intramolecular hydrogen bonds involving the hydroxyl groups and the amino group contribute to the stabilisation of five different conformations observed in the broadband rotational spectrum.
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spelling pubmed-47669592016-03-08 Intramolecular interactions in the polar headgroup of sphingosine: serinol Loru, Donatella Peña, Isabel Alonso, José L. Eugenia Sanz, M. Chem Commun (Camb) Chemistry The intramolecular interactions in the lipid sphingosine have been elucidated through the investigation of the amino alcohol serinol which mimics its polar headgroup. Intricate networks of intramolecular hydrogen bonds involving the hydroxyl groups and the amino group contribute to the stabilisation of five different conformations observed in the broadband rotational spectrum. Royal Society of Chemistry 2016-03-04 2016-01-04 /pmc/articles/PMC4766959/ /pubmed/26727395 http://dx.doi.org/10.1039/c5cc09423b Text en This journal is © The Royal Society of Chemistry 2016 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Loru, Donatella
Peña, Isabel
Alonso, José L.
Eugenia Sanz, M.
Intramolecular interactions in the polar headgroup of sphingosine: serinol
title Intramolecular interactions in the polar headgroup of sphingosine: serinol
title_full Intramolecular interactions in the polar headgroup of sphingosine: serinol
title_fullStr Intramolecular interactions in the polar headgroup of sphingosine: serinol
title_full_unstemmed Intramolecular interactions in the polar headgroup of sphingosine: serinol
title_short Intramolecular interactions in the polar headgroup of sphingosine: serinol
title_sort intramolecular interactions in the polar headgroup of sphingosine: serinol
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4766959/
https://www.ncbi.nlm.nih.gov/pubmed/26727395
http://dx.doi.org/10.1039/c5cc09423b
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AT penaisabel intramolecularinteractionsinthepolarheadgroupofsphingosineserinol
AT alonsojosel intramolecularinteractionsinthepolarheadgroupofsphingosineserinol
AT eugeniasanzm intramolecularinteractionsinthepolarheadgroupofsphingosineserinol

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