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Crystal structure of fac-tricarbon­yl(quinoline-2-carboxyl­ato-κ(2) N,O)(tri­phenyl­arsane-κAs)rhenium(I)

In the title compound, [Re(C(10)H(6)NO(2))(CO)(3){As(C(6)H(5))(3)}], the coordination environment of Re(I) is that of a distorted octa­hedron. Three coordination sites are occupied by three carbonyl groups in a facial arrangement and the remaining three sites by tri­phenyl­arsane and deprotonated qu...

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Autores principales: Triantis, Charalampos, Shegani, Antonio, Kiritsis, Christos, Raptopoulou, Catherine P., Psycharis, Vassilis, Pelecanou, Maria, Pirmettis, Ioannis, Papadopoulos, Minas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770954/
https://www.ncbi.nlm.nih.gov/pubmed/26958366
http://dx.doi.org/10.1107/S2056989015024640
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author Triantis, Charalampos
Shegani, Antonio
Kiritsis, Christos
Raptopoulou, Catherine P.
Psycharis, Vassilis
Pelecanou, Maria
Pirmettis, Ioannis
Papadopoulos, Minas
author_facet Triantis, Charalampos
Shegani, Antonio
Kiritsis, Christos
Raptopoulou, Catherine P.
Psycharis, Vassilis
Pelecanou, Maria
Pirmettis, Ioannis
Papadopoulos, Minas
author_sort Triantis, Charalampos
collection PubMed
description In the title compound, [Re(C(10)H(6)NO(2))(CO)(3){As(C(6)H(5))(3)}], the coordination environment of Re(I) is that of a distorted octa­hedron. Three coordination sites are occupied by three carbonyl groups in a facial arrangement and the remaining three sites by tri­phenyl­arsane and deprotonated quinaldic acid in As-mono- and N,O-bidentate fashions, respectively. In the crystal, the complexes are linked through weak C—H⋯O hydrogen bonds, forming a three-dimensional network. It worth noting that, as far as we know, this complex is the first Re(I) tri­phenyl­arsane tricarbonyl compound to be reported.
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spelling pubmed-47709542016-03-08 Crystal structure of fac-tricarbon­yl(quinoline-2-carboxyl­ato-κ(2) N,O)(tri­phenyl­arsane-κAs)rhenium(I) Triantis, Charalampos Shegani, Antonio Kiritsis, Christos Raptopoulou, Catherine P. Psycharis, Vassilis Pelecanou, Maria Pirmettis, Ioannis Papadopoulos, Minas Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Re(C(10)H(6)NO(2))(CO)(3){As(C(6)H(5))(3)}], the coordination environment of Re(I) is that of a distorted octa­hedron. Three coordination sites are occupied by three carbonyl groups in a facial arrangement and the remaining three sites by tri­phenyl­arsane and deprotonated quinaldic acid in As-mono- and N,O-bidentate fashions, respectively. In the crystal, the complexes are linked through weak C—H⋯O hydrogen bonds, forming a three-dimensional network. It worth noting that, as far as we know, this complex is the first Re(I) tri­phenyl­arsane tricarbonyl compound to be reported. International Union of Crystallography 2016-01-06 /pmc/articles/PMC4770954/ /pubmed/26958366 http://dx.doi.org/10.1107/S2056989015024640 Text en © Triantis et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Triantis, Charalampos
Shegani, Antonio
Kiritsis, Christos
Raptopoulou, Catherine P.
Psycharis, Vassilis
Pelecanou, Maria
Pirmettis, Ioannis
Papadopoulos, Minas
Crystal structure of fac-tricarbon­yl(quinoline-2-carboxyl­ato-κ(2) N,O)(tri­phenyl­arsane-κAs)rhenium(I)
title Crystal structure of fac-tricarbon­yl(quinoline-2-carboxyl­ato-κ(2) N,O)(tri­phenyl­arsane-κAs)rhenium(I)
title_full Crystal structure of fac-tricarbon­yl(quinoline-2-carboxyl­ato-κ(2) N,O)(tri­phenyl­arsane-κAs)rhenium(I)
title_fullStr Crystal structure of fac-tricarbon­yl(quinoline-2-carboxyl­ato-κ(2) N,O)(tri­phenyl­arsane-κAs)rhenium(I)
title_full_unstemmed Crystal structure of fac-tricarbon­yl(quinoline-2-carboxyl­ato-κ(2) N,O)(tri­phenyl­arsane-κAs)rhenium(I)
title_short Crystal structure of fac-tricarbon­yl(quinoline-2-carboxyl­ato-κ(2) N,O)(tri­phenyl­arsane-κAs)rhenium(I)
title_sort crystal structure of fac-tricarbon­yl(quinoline-2-carboxyl­ato-κ(2) n,o)(tri­phenyl­arsane-κas)rhenium(i)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770954/
https://www.ncbi.nlm.nih.gov/pubmed/26958366
http://dx.doi.org/10.1107/S2056989015024640
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