Crystal structure of (2Z,5Z)-3-(4-meth­oxy­phen­yl)-2-[(4-meth­oxy­phenyl)­imino]-5-[(E)-3-(2-nitro­phen­yl)allyl­idene]-1,3-thia­zolidin-4-one

In the title compound, C(26)H(21)N(3)O(5)S, the thia­zole ring is nearly planar with a maximum deviation of 0.017 (2) Å, and is twisted with respect to the three benzene rings, making dihedral angles of 25.52 (12), 85.77 (12) and 81.85 (13)°. In the crystal, weak C—H⋯O hydrogen bonds and C—H⋯π inter...

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Autores principales: Rahmani, Rachida, Djafri, Ahmed, Daran, Jean-Claude, Djafri, Ayada, Chouaih, Abdelkader, Hamzaoui, Fodil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770957/
https://www.ncbi.nlm.nih.gov/pubmed/26958377
http://dx.doi.org/10.1107/S2056989016000207
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author Rahmani, Rachida
Djafri, Ahmed
Daran, Jean-Claude
Djafri, Ayada
Chouaih, Abdelkader
Hamzaoui, Fodil
author_facet Rahmani, Rachida
Djafri, Ahmed
Daran, Jean-Claude
Djafri, Ayada
Chouaih, Abdelkader
Hamzaoui, Fodil
author_sort Rahmani, Rachida
collection PubMed
description In the title compound, C(26)H(21)N(3)O(5)S, the thia­zole ring is nearly planar with a maximum deviation of 0.017 (2) Å, and is twisted with respect to the three benzene rings, making dihedral angles of 25.52 (12), 85.77 (12) and 81.85 (13)°. In the crystal, weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions link the mol­ecules into a three-dimensional supra­molecular architecture. Aromatic π–π stacking is also observed between the parallel nitro­benzene rings of neighbouring mol­ecules, the centroid-to-centroid distance being 3.5872 (15) Å.
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spelling pubmed-47709572016-03-08 Crystal structure of (2Z,5Z)-3-(4-meth­oxy­phen­yl)-2-[(4-meth­oxy­phenyl)­imino]-5-[(E)-3-(2-nitro­phen­yl)allyl­idene]-1,3-thia­zolidin-4-one Rahmani, Rachida Djafri, Ahmed Daran, Jean-Claude Djafri, Ayada Chouaih, Abdelkader Hamzaoui, Fodil Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(26)H(21)N(3)O(5)S, the thia­zole ring is nearly planar with a maximum deviation of 0.017 (2) Å, and is twisted with respect to the three benzene rings, making dihedral angles of 25.52 (12), 85.77 (12) and 81.85 (13)°. In the crystal, weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions link the mol­ecules into a three-dimensional supra­molecular architecture. Aromatic π–π stacking is also observed between the parallel nitro­benzene rings of neighbouring mol­ecules, the centroid-to-centroid distance being 3.5872 (15) Å. International Union of Crystallography 2016-01-13 /pmc/articles/PMC4770957/ /pubmed/26958377 http://dx.doi.org/10.1107/S2056989016000207 Text en © Rahmani et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Rahmani, Rachida
Djafri, Ahmed
Daran, Jean-Claude
Djafri, Ayada
Chouaih, Abdelkader
Hamzaoui, Fodil
Crystal structure of (2Z,5Z)-3-(4-meth­oxy­phen­yl)-2-[(4-meth­oxy­phenyl)­imino]-5-[(E)-3-(2-nitro­phen­yl)allyl­idene]-1,3-thia­zolidin-4-one
title Crystal structure of (2Z,5Z)-3-(4-meth­oxy­phen­yl)-2-[(4-meth­oxy­phenyl)­imino]-5-[(E)-3-(2-nitro­phen­yl)allyl­idene]-1,3-thia­zolidin-4-one
title_full Crystal structure of (2Z,5Z)-3-(4-meth­oxy­phen­yl)-2-[(4-meth­oxy­phenyl)­imino]-5-[(E)-3-(2-nitro­phen­yl)allyl­idene]-1,3-thia­zolidin-4-one
title_fullStr Crystal structure of (2Z,5Z)-3-(4-meth­oxy­phen­yl)-2-[(4-meth­oxy­phenyl)­imino]-5-[(E)-3-(2-nitro­phen­yl)allyl­idene]-1,3-thia­zolidin-4-one
title_full_unstemmed Crystal structure of (2Z,5Z)-3-(4-meth­oxy­phen­yl)-2-[(4-meth­oxy­phenyl)­imino]-5-[(E)-3-(2-nitro­phen­yl)allyl­idene]-1,3-thia­zolidin-4-one
title_short Crystal structure of (2Z,5Z)-3-(4-meth­oxy­phen­yl)-2-[(4-meth­oxy­phenyl)­imino]-5-[(E)-3-(2-nitro­phen­yl)allyl­idene]-1,3-thia­zolidin-4-one
title_sort crystal structure of (2z,5z)-3-(4-meth­oxy­phen­yl)-2-[(4-meth­oxy­phenyl)­imino]-5-[(e)-3-(2-nitro­phen­yl)allyl­idene]-1,3-thia­zolidin-4-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770957/
https://www.ncbi.nlm.nih.gov/pubmed/26958377
http://dx.doi.org/10.1107/S2056989016000207
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