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Crystal structure of an organic–inorganic supramolecular salt based on a 4,4′-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a β-octamolybdate anion
The asymmetric unit of the title compound, bis[4,4′-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium)] β-octamolybdate, (C(11)H(18)N(4))(2)[Mo(8)O(26)] or (H(4)mbdpz)(2)[Mo(8)O(26)], is composed of an H(4)mbdpz(2+) cation and half of the β-octamolybdate anion which is completed by inversion symmetry....
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770958/ https://www.ncbi.nlm.nih.gov/pubmed/26958369 http://dx.doi.org/10.1107/S2056989015024524 |
Sumario: | The asymmetric unit of the title compound, bis[4,4′-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium)] β-octamolybdate, (C(11)H(18)N(4))(2)[Mo(8)O(26)] or (H(4)mbdpz)(2)[Mo(8)O(26)], is composed of an H(4)mbdpz(2+) cation and half of the β-octamolybdate anion which is completed by inversion symmetry. The organic molecular units are engaged in a series of N—H⋯O hydrogen bonds with neighbouring anions, with N⋯O distances and N—H⋯O angles in the ranges 2.730 (2)–2.941 (2) Å and 122–166°, respectively. These interactions lead to the formation of a supramolecular two-dimensional network parallel to the (010) plane. |
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