Crystal structure of an organic–inorganic supra­molecular salt based on a 4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a β-octa­molybdate anion

The asymmetric unit of the title compound, bis­[4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium)] β-octa­molybdate, (C(11)H(18)N(4))(2)[Mo(8)O(26)] or (H(4)mbdpz)(2)[Mo(8)O(26)], is composed of an H(4)mbdpz(2+) cation and half of the β-octa­molybdate anion which is completed by inversion symmetry....

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Autores principales: Amarante, Tatiana R., Gonçalves, Isabel S., Almeida Paz, Filipe A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770958/
https://www.ncbi.nlm.nih.gov/pubmed/26958369
http://dx.doi.org/10.1107/S2056989015024524
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author Amarante, Tatiana R.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_facet Amarante, Tatiana R.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_sort Amarante, Tatiana R.
collection PubMed
description The asymmetric unit of the title compound, bis­[4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium)] β-octa­molybdate, (C(11)H(18)N(4))(2)[Mo(8)O(26)] or (H(4)mbdpz)(2)[Mo(8)O(26)], is composed of an H(4)mbdpz(2+) cation and half of the β-octa­molybdate anion which is completed by inversion symmetry. The organic mol­ecular units are engaged in a series of N—H⋯O hydrogen bonds with neighbouring anions, with N⋯O distances and N—H⋯O angles in the ranges 2.730 (2)–2.941 (2) Å and 122–166°, respectively. These inter­actions lead to the formation of a supra­molecular two-dimensional network parallel to the (010) plane.
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spelling pubmed-47709582016-03-08 Crystal structure of an organic–inorganic supra­molecular salt based on a 4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a β-octa­molybdate anion Amarante, Tatiana R. Gonçalves, Isabel S. Almeida Paz, Filipe A. Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, bis­[4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium)] β-octa­molybdate, (C(11)H(18)N(4))(2)[Mo(8)O(26)] or (H(4)mbdpz)(2)[Mo(8)O(26)], is composed of an H(4)mbdpz(2+) cation and half of the β-octa­molybdate anion which is completed by inversion symmetry. The organic mol­ecular units are engaged in a series of N—H⋯O hydrogen bonds with neighbouring anions, with N⋯O distances and N—H⋯O angles in the ranges 2.730 (2)–2.941 (2) Å and 122–166°, respectively. These inter­actions lead to the formation of a supra­molecular two-dimensional network parallel to the (010) plane. International Union of Crystallography 2016-01-06 /pmc/articles/PMC4770958/ /pubmed/26958369 http://dx.doi.org/10.1107/S2056989015024524 Text en © Amarante et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Amarante, Tatiana R.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
Crystal structure of an organic–inorganic supra­molecular salt based on a 4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a β-octa­molybdate anion
title Crystal structure of an organic–inorganic supra­molecular salt based on a 4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a β-octa­molybdate anion
title_full Crystal structure of an organic–inorganic supra­molecular salt based on a 4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a β-octa­molybdate anion
title_fullStr Crystal structure of an organic–inorganic supra­molecular salt based on a 4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a β-octa­molybdate anion
title_full_unstemmed Crystal structure of an organic–inorganic supra­molecular salt based on a 4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a β-octa­molybdate anion
title_short Crystal structure of an organic–inorganic supra­molecular salt based on a 4,4′-methyl­enebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a β-octa­molybdate anion
title_sort crystal structure of an organic–inorganic supra­molecular salt based on a 4,4′-methyl­enebis(3,5-dimethyl-1h-pyrazol-2-ium) cation and a β-octa­molybdate anion
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770958/
https://www.ncbi.nlm.nih.gov/pubmed/26958369
http://dx.doi.org/10.1107/S2056989015024524
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