Poly[μ(2)-aqua-aqua­[μ(3)-N-butyl-N-(2-hy­droxy­ethyl)di­thio­carbamato-κ(3) O,O′:S]sodium]

In the title compound, [Na(C(7)H(14)NOS(2))(H(2)O)(2)](n), the Na(I) cation is coordinated by five O atoms [Na—O = 2.3142 (11)–2.4677 (10) Å] from three aqua and two N-butyl-N-(2-hy­droxy­eth­yl)di­thio­carbamate (L) ligands and one S atom [Na—S = 3.0074 (6) Å] from a third L ligand in a highly dist...

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Detalles Bibliográficos
Autores principales: Bhat, Muzzaffar A., Jain, Shalini, Srivastava, Sanjay K., Butcher, Ray J., Wikaira, Jan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770959/
https://www.ncbi.nlm.nih.gov/pubmed/26958386
http://dx.doi.org/10.1107/S2056989016000657
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author Bhat, Muzzaffar A.
Jain, Shalini
Srivastava, Sanjay K.
Butcher, Ray J.
Wikaira, Jan
author_facet Bhat, Muzzaffar A.
Jain, Shalini
Srivastava, Sanjay K.
Butcher, Ray J.
Wikaira, Jan
author_sort Bhat, Muzzaffar A.
collection PubMed
description In the title compound, [Na(C(7)H(14)NOS(2))(H(2)O)(2)](n), the Na(I) cation is coordinated by five O atoms [Na—O = 2.3142 (11)–2.4677 (10) Å] from three aqua and two N-butyl-N-(2-hy­droxy­eth­yl)di­thio­carbamate (L) ligands and one S atom [Na—S = 3.0074 (6) Å] from a third L ligand in a highly distorted octa­hedral geometry. Two aqua ligands related by an inversion center bridge two Na(I) cations, and each L ligand coordinates three Na(I) cations, leading to a layered arrangement aligned parallel to the bc plane. Inter­molecular O—H⋯S hydrogen bonds are observed in the inner part of each polymeric layer; these are packed along the a axis and held together by weak van der Waals forces.
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spelling pubmed-47709592016-03-08 Poly[μ(2)-aqua-aqua­[μ(3)-N-butyl-N-(2-hy­droxy­ethyl)di­thio­carbamato-κ(3) O,O′:S]sodium] Bhat, Muzzaffar A. Jain, Shalini Srivastava, Sanjay K. Butcher, Ray J. Wikaira, Jan Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Na(C(7)H(14)NOS(2))(H(2)O)(2)](n), the Na(I) cation is coordinated by five O atoms [Na—O = 2.3142 (11)–2.4677 (10) Å] from three aqua and two N-butyl-N-(2-hy­droxy­eth­yl)di­thio­carbamate (L) ligands and one S atom [Na—S = 3.0074 (6) Å] from a third L ligand in a highly distorted octa­hedral geometry. Two aqua ligands related by an inversion center bridge two Na(I) cations, and each L ligand coordinates three Na(I) cations, leading to a layered arrangement aligned parallel to the bc plane. Inter­molecular O—H⋯S hydrogen bonds are observed in the inner part of each polymeric layer; these are packed along the a axis and held together by weak van der Waals forces. International Union of Crystallography 2016-01-20 /pmc/articles/PMC4770959/ /pubmed/26958386 http://dx.doi.org/10.1107/S2056989016000657 Text en © Bhat et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Bhat, Muzzaffar A.
Jain, Shalini
Srivastava, Sanjay K.
Butcher, Ray J.
Wikaira, Jan
Poly[μ(2)-aqua-aqua­[μ(3)-N-butyl-N-(2-hy­droxy­ethyl)di­thio­carbamato-κ(3) O,O′:S]sodium]
title Poly[μ(2)-aqua-aqua­[μ(3)-N-butyl-N-(2-hy­droxy­ethyl)di­thio­carbamato-κ(3) O,O′:S]sodium]
title_full Poly[μ(2)-aqua-aqua­[μ(3)-N-butyl-N-(2-hy­droxy­ethyl)di­thio­carbamato-κ(3) O,O′:S]sodium]
title_fullStr Poly[μ(2)-aqua-aqua­[μ(3)-N-butyl-N-(2-hy­droxy­ethyl)di­thio­carbamato-κ(3) O,O′:S]sodium]
title_full_unstemmed Poly[μ(2)-aqua-aqua­[μ(3)-N-butyl-N-(2-hy­droxy­ethyl)di­thio­carbamato-κ(3) O,O′:S]sodium]
title_short Poly[μ(2)-aqua-aqua­[μ(3)-N-butyl-N-(2-hy­droxy­ethyl)di­thio­carbamato-κ(3) O,O′:S]sodium]
title_sort poly[μ(2)-aqua-aqua­[μ(3)-n-butyl-n-(2-hy­droxy­ethyl)di­thio­carbamato-κ(3) o,o′:s]sodium]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770959/
https://www.ncbi.nlm.nih.gov/pubmed/26958386
http://dx.doi.org/10.1107/S2056989016000657
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