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Crystal structure of 1-benzyl-4-formyl-1H-pyrrole-3-carboxamide
In the title compound, C(13)H(12)N(2)O(2) (I), the mean planes of the pyrrole and benzyl rings are approximately perpendicular, forming a dihedral angle of 87.07 (4) °. There is an intramolecular N—H⋯O hydrogen bond forming an S(7) ring motif. In the crystal, molecules are linked via a pair of N—H...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770961/ https://www.ncbi.nlm.nih.gov/pubmed/26958371 http://dx.doi.org/10.1107/S2056989016000128 |
Sumario: | In the title compound, C(13)H(12)N(2)O(2) (I), the mean planes of the pyrrole and benzyl rings are approximately perpendicular, forming a dihedral angle of 87.07 (4) °. There is an intramolecular N—H⋯O hydrogen bond forming an S(7) ring motif. In the crystal, molecules are linked via a pair of N—H⋯O hydrogen bonds forming inversion dimers. C—H⋯O hydrogen bonds link the dimers into chains along direction [10-1]. The chains are further linked by weak C—H⋯π interactions forming layers parallel to the ac plane. |
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