Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]cadmium

In the structure of the title compound, [Cd(C(8)H(6)NO(4))(2)(C(3)H(10)N(2))(2)], the Cd(II) atom is located on a center of symmetry with one independent Cd—O distance of 2.3547 (17) Å and two Cd—N distances of 2.3265 (18) and 2.3449 (19) Å. The Cd(II) atom has an overall octa­hedral coordination en...

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Autores principales: Rahn, Ian M., Crawford, Carlos L., Assefa, Zerihun, Hendrich, Jeffery, Sykora, Richard E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770970/
https://www.ncbi.nlm.nih.gov/pubmed/26958394
http://dx.doi.org/10.1107/S2056989016000943
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author Rahn, Ian M.
Crawford, Carlos L.
Assefa, Zerihun
Hendrich, Jeffery
Sykora, Richard E.
author_facet Rahn, Ian M.
Crawford, Carlos L.
Assefa, Zerihun
Hendrich, Jeffery
Sykora, Richard E.
author_sort Rahn, Ian M.
collection PubMed
description In the structure of the title compound, [Cd(C(8)H(6)NO(4))(2)(C(3)H(10)N(2))(2)], the Cd(II) atom is located on a center of symmetry with one independent Cd—O distance of 2.3547 (17) Å and two Cd—N distances of 2.3265 (18) and 2.3449 (19) Å. The Cd(II) atom has an overall octa­hedral coordination environment. Several types of hydrogen-bonding inter­actions are evident. Both intra- and inter­molecular inter­actions occur between the amino groups and the O atoms of the acetate group. These N—H⋯O hydrogen bonds lead to a layered structure extending parallel to the bc plane. In addition, weak inter­molecular C—H⋯O inter­actions involving the nitro groups exist, leading to the formation of a three-dimensional network structure.
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spelling pubmed-47709702016-03-08 Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]cadmium Rahn, Ian M. Crawford, Carlos L. Assefa, Zerihun Hendrich, Jeffery Sykora, Richard E. Acta Crystallogr E Crystallogr Commun Research Communications In the structure of the title compound, [Cd(C(8)H(6)NO(4))(2)(C(3)H(10)N(2))(2)], the Cd(II) atom is located on a center of symmetry with one independent Cd—O distance of 2.3547 (17) Å and two Cd—N distances of 2.3265 (18) and 2.3449 (19) Å. The Cd(II) atom has an overall octa­hedral coordination environment. Several types of hydrogen-bonding inter­actions are evident. Both intra- and inter­molecular inter­actions occur between the amino groups and the O atoms of the acetate group. These N—H⋯O hydrogen bonds lead to a layered structure extending parallel to the bc plane. In addition, weak inter­molecular C—H⋯O inter­actions involving the nitro groups exist, leading to the formation of a three-dimensional network structure. International Union of Crystallography 2016-01-23 /pmc/articles/PMC4770970/ /pubmed/26958394 http://dx.doi.org/10.1107/S2056989016000943 Text en © Rahn et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Rahn, Ian M.
Crawford, Carlos L.
Assefa, Zerihun
Hendrich, Jeffery
Sykora, Richard E.
Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]cadmium
title Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]cadmium
title_full Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]cadmium
title_fullStr Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]cadmium
title_full_unstemmed Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]cadmium
title_short Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]cadmium
title_sort crystal structure of bis­(1,3-di­amino­propane-κ(2) n,n′)bis­[2-(4-nitro­phen­yl)acetato-κo]cadmium
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770970/
https://www.ncbi.nlm.nih.gov/pubmed/26958394
http://dx.doi.org/10.1107/S2056989016000943
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