Crystal structure of (n-but­yl)[2-(2,6-di­meth­oxy­phen­yl)-6-methyl­phen­yl](2-meth­oxy­phen­yl)phospho­nium chloride monohydrate

The title hydrated salt, C(26)H(32)O(3)P(+)·Cl(−)·H(2)O, contains four different substit­uents (H, alkyl, aryl, and biar­yl) on the P atom. The P—H hydrogen atom of the phospho­nium ion was located in a difference Fourier map and refined without imposing additional restraints. In the crystal, the Cl...

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Detalles Bibliográficos
Autores principales: Feng, Ge, Filatov, Alexander S., Jordan, Richard F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770974/
https://www.ncbi.nlm.nih.gov/pubmed/26958381
http://dx.doi.org/10.1107/S2056989015024780
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author Feng, Ge
Filatov, Alexander S.
Jordan, Richard F.
author_facet Feng, Ge
Filatov, Alexander S.
Jordan, Richard F.
author_sort Feng, Ge
collection PubMed
description The title hydrated salt, C(26)H(32)O(3)P(+)·Cl(−)·H(2)O, contains four different substit­uents (H, alkyl, aryl, and biar­yl) on the P atom. The P—H hydrogen atom of the phospho­nium ion was located in a difference Fourier map and refined without imposing additional restraints. In the crystal, the Cl(−) ions and water mol­ecules are linked by pairs of O(water)—H⋯Cl(−) hydrogen bonds and further linked to the phospho­nium cation by P—H(+)⋯Cl(−) and C(Ar/OMe)—H⋯O(water) hydrogen bonds to form an infinite one-dimensional chain along the [010] direction.
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spelling pubmed-47709742016-03-08 Crystal structure of (n-but­yl)[2-(2,6-di­meth­oxy­phen­yl)-6-methyl­phen­yl](2-meth­oxy­phen­yl)phospho­nium chloride monohydrate Feng, Ge Filatov, Alexander S. Jordan, Richard F. Acta Crystallogr E Crystallogr Commun Research Communications The title hydrated salt, C(26)H(32)O(3)P(+)·Cl(−)·H(2)O, contains four different substit­uents (H, alkyl, aryl, and biar­yl) on the P atom. The P—H hydrogen atom of the phospho­nium ion was located in a difference Fourier map and refined without imposing additional restraints. In the crystal, the Cl(−) ions and water mol­ecules are linked by pairs of O(water)—H⋯Cl(−) hydrogen bonds and further linked to the phospho­nium cation by P—H(+)⋯Cl(−) and C(Ar/OMe)—H⋯O(water) hydrogen bonds to form an infinite one-dimensional chain along the [010] direction. International Union of Crystallography 2016-01-13 /pmc/articles/PMC4770974/ /pubmed/26958381 http://dx.doi.org/10.1107/S2056989015024780 Text en © Feng et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Feng, Ge
Filatov, Alexander S.
Jordan, Richard F.
Crystal structure of (n-but­yl)[2-(2,6-di­meth­oxy­phen­yl)-6-methyl­phen­yl](2-meth­oxy­phen­yl)phospho­nium chloride monohydrate
title Crystal structure of (n-but­yl)[2-(2,6-di­meth­oxy­phen­yl)-6-methyl­phen­yl](2-meth­oxy­phen­yl)phospho­nium chloride monohydrate
title_full Crystal structure of (n-but­yl)[2-(2,6-di­meth­oxy­phen­yl)-6-methyl­phen­yl](2-meth­oxy­phen­yl)phospho­nium chloride monohydrate
title_fullStr Crystal structure of (n-but­yl)[2-(2,6-di­meth­oxy­phen­yl)-6-methyl­phen­yl](2-meth­oxy­phen­yl)phospho­nium chloride monohydrate
title_full_unstemmed Crystal structure of (n-but­yl)[2-(2,6-di­meth­oxy­phen­yl)-6-methyl­phen­yl](2-meth­oxy­phen­yl)phospho­nium chloride monohydrate
title_short Crystal structure of (n-but­yl)[2-(2,6-di­meth­oxy­phen­yl)-6-methyl­phen­yl](2-meth­oxy­phen­yl)phospho­nium chloride monohydrate
title_sort crystal structure of (n-but­yl)[2-(2,6-di­meth­oxy­phen­yl)-6-methyl­phen­yl](2-meth­oxy­phen­yl)phospho­nium chloride monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770974/
https://www.ncbi.nlm.nih.gov/pubmed/26958381
http://dx.doi.org/10.1107/S2056989015024780
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