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Crystal structure of aqua­(nitrato-κO)dioxido{2-[3-(pyridin-2-yl-κN)-1H-1,2,4-triazol-5-yl-κN (4)]phenolato-κO}uranium(VI) aceto­nitrile monosolvate monohydrate

In the title compound, [U(C(13)H(9)N(4)O)(NO(3))O(2)(H(2)O)]·CH(3)CN·H(2)O, the U(VI) atom is seven-coordinated in a distorted penta­gonal–bipyramidal N(2)O(5) manner by one tridentate triazole ligand, one monodentate nitrate anion and one water mol­ecule in the equatorial plane and by two uran­yl(V...

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Detalles Bibliográficos
Autores principales: Vashchenko, Oleksandr, Raspertova, Ilona, Dyakonenko, Viktoriya, Shishkina, Svitlana, Khomenko, Dmytro, Doroschuk, Roman, Lampeka, Rostislav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770975/
https://www.ncbi.nlm.nih.gov/pubmed/26958365
http://dx.doi.org/10.1107/S205698901502438X
Descripción
Sumario:In the title compound, [U(C(13)H(9)N(4)O)(NO(3))O(2)(H(2)O)]·CH(3)CN·H(2)O, the U(VI) atom is seven-coordinated in a distorted penta­gonal–bipyramidal N(2)O(5) manner by one tridentate triazole ligand, one monodentate nitrate anion and one water mol­ecule in the equatorial plane and by two uran­yl(VI) O atoms in the axial positions. In the crystal, the U(VI) complex mol­ecule is linked to the water and aceto­nitrile solvent mol­ecules through N—H⋯N, O—H⋯O and O—H⋯N hydrogen bonds, forming a sheet structure parallel to the bc plane. The sheets are further linked by an additional O—H⋯O hydrogen bond, forming a three-dimensional network.