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Crystal structure of diethyl 2-acet­oxy-2-[3-(4-nitro­phen­yl)-3-oxo-1-phenyl­prop­yl]malonate

In the racemic title compound, C(24)H(25)NO(9), the dihedral angle between the planes of the two benzene-ring systems is 80.16 (6)°, while the side-chain conformation is stabilized by a methyl­ene–carboxyl C—H⋯O hydrogen bond. Weak inter­molecular C—H⋯O hydrogen bonds form inversion dimers [graph se...

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Detalles Bibliográficos
Autores principales: May, Nóra Veronika, Gál, Gyula Tamás, Rapi, Zsolt, Bakó, Péter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770977/
https://www.ncbi.nlm.nih.gov/pubmed/26958401
http://dx.doi.org/10.1107/S2056989016001432
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author May, Nóra Veronika
Gál, Gyula Tamás
Rapi, Zsolt
Bakó, Péter
author_facet May, Nóra Veronika
Gál, Gyula Tamás
Rapi, Zsolt
Bakó, Péter
author_sort May, Nóra Veronika
collection PubMed
description In the racemic title compound, C(24)H(25)NO(9), the dihedral angle between the planes of the two benzene-ring systems is 80.16 (6)°, while the side-chain conformation is stabilized by a methyl­ene–carboxyl C—H⋯O hydrogen bond. Weak inter­molecular C—H⋯O hydrogen bonds form inversion dimers [graph set R (2) (2)(16)] which are linked into chains extending along a. Further C—H⋯O hydrogen bonding extends the structure along b through cyclic R (2) (2)(10) motifs. Although no π–π aromatic ring inter­actions are present in the structure, C—H⋯π ring inter­actions across c generate an overall three-dimensional supra­molecular structure.
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spelling pubmed-47709772016-03-08 Crystal structure of diethyl 2-acet­oxy-2-[3-(4-nitro­phen­yl)-3-oxo-1-phenyl­prop­yl]malonate May, Nóra Veronika Gál, Gyula Tamás Rapi, Zsolt Bakó, Péter Acta Crystallogr E Crystallogr Commun Research Communications In the racemic title compound, C(24)H(25)NO(9), the dihedral angle between the planes of the two benzene-ring systems is 80.16 (6)°, while the side-chain conformation is stabilized by a methyl­ene–carboxyl C—H⋯O hydrogen bond. Weak inter­molecular C—H⋯O hydrogen bonds form inversion dimers [graph set R (2) (2)(16)] which are linked into chains extending along a. Further C—H⋯O hydrogen bonding extends the structure along b through cyclic R (2) (2)(10) motifs. Although no π–π aromatic ring inter­actions are present in the structure, C—H⋯π ring inter­actions across c generate an overall three-dimensional supra­molecular structure. International Union of Crystallography 2016-01-27 /pmc/articles/PMC4770977/ /pubmed/26958401 http://dx.doi.org/10.1107/S2056989016001432 Text en © May et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
May, Nóra Veronika
Gál, Gyula Tamás
Rapi, Zsolt
Bakó, Péter
Crystal structure of diethyl 2-acet­oxy-2-[3-(4-nitro­phen­yl)-3-oxo-1-phenyl­prop­yl]malonate
title Crystal structure of diethyl 2-acet­oxy-2-[3-(4-nitro­phen­yl)-3-oxo-1-phenyl­prop­yl]malonate
title_full Crystal structure of diethyl 2-acet­oxy-2-[3-(4-nitro­phen­yl)-3-oxo-1-phenyl­prop­yl]malonate
title_fullStr Crystal structure of diethyl 2-acet­oxy-2-[3-(4-nitro­phen­yl)-3-oxo-1-phenyl­prop­yl]malonate
title_full_unstemmed Crystal structure of diethyl 2-acet­oxy-2-[3-(4-nitro­phen­yl)-3-oxo-1-phenyl­prop­yl]malonate
title_short Crystal structure of diethyl 2-acet­oxy-2-[3-(4-nitro­phen­yl)-3-oxo-1-phenyl­prop­yl]malonate
title_sort crystal structure of diethyl 2-acet­oxy-2-[3-(4-nitro­phen­yl)-3-oxo-1-phenyl­prop­yl]malonate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770977/
https://www.ncbi.nlm.nih.gov/pubmed/26958401
http://dx.doi.org/10.1107/S2056989016001432
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