Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenyl­spiro­[2.5]octane-1-carbaldehyde

In the title compound, C(17)H(18)O(3), the two non-spiro C atoms of the cyclo­propane ring bear a formyl and a phenyl substituent which are trans-oriented. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯π contacts resulting in a three-dimensional supra­molecular structure.

Detalles Bibliográficos
Autores principales: Chelli, Saloua, Troshin, Konstantin, Lakhdar, Sami, Mayr, Herbert, Mayer, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770978/
https://www.ncbi.nlm.nih.gov/pubmed/26958403
http://dx.doi.org/10.1107/S205698901600164X
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author Chelli, Saloua
Troshin, Konstantin
Lakhdar, Sami
Mayr, Herbert
Mayer, Peter
author_facet Chelli, Saloua
Troshin, Konstantin
Lakhdar, Sami
Mayr, Herbert
Mayer, Peter
author_sort Chelli, Saloua
collection PubMed
description In the title compound, C(17)H(18)O(3), the two non-spiro C atoms of the cyclo­propane ring bear a formyl and a phenyl substituent which are trans-oriented. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯π contacts resulting in a three-dimensional supra­molecular structure.
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spelling pubmed-47709782016-03-08 Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenyl­spiro­[2.5]octane-1-carbaldehyde Chelli, Saloua Troshin, Konstantin Lakhdar, Sami Mayr, Herbert Mayer, Peter Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(17)H(18)O(3), the two non-spiro C atoms of the cyclo­propane ring bear a formyl and a phenyl substituent which are trans-oriented. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯π contacts resulting in a three-dimensional supra­molecular structure. International Union of Crystallography 2016-01-30 /pmc/articles/PMC4770978/ /pubmed/26958403 http://dx.doi.org/10.1107/S205698901600164X Text en © Chelli et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Chelli, Saloua
Troshin, Konstantin
Lakhdar, Sami
Mayr, Herbert
Mayer, Peter
Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenyl­spiro­[2.5]octane-1-carbaldehyde
title Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenyl­spiro­[2.5]octane-1-carbaldehyde
title_full Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenyl­spiro­[2.5]octane-1-carbaldehyde
title_fullStr Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenyl­spiro­[2.5]octane-1-carbaldehyde
title_full_unstemmed Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenyl­spiro­[2.5]octane-1-carbaldehyde
title_short Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenyl­spiro­[2.5]octane-1-carbaldehyde
title_sort crystal structure of (1s,2r)-6,6-dimethyl-4,8-dioxo-2-phenyl­spiro­[2.5]octane-1-carbaldehyde
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4770978/
https://www.ncbi.nlm.nih.gov/pubmed/26958403
http://dx.doi.org/10.1107/S205698901600164X
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