Symmetry reduction due to gallium substitution in the garnet Li(6.43(2))Ga(0.52(3))La(2.67(4))Zr(2)O(12)

Single-crystal structure refinements on lithium lanthanum zirconate (LLZO; Li(7)La(3)Zr(2)O(12)) substituted with gallium were successfully carried out in the cubic symmetry space group I [Image: see text]3d. Gallium was found on two lithium sites as well as on the lanthanum position. Due to the str...

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Autores principales: Robben, Lars, Merzlyakova, Elena, Heitjans, Paul, Gesing, Thorsten M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778807/
https://www.ncbi.nlm.nih.gov/pubmed/27006788
http://dx.doi.org/10.1107/S2056989016001924
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author Robben, Lars
Merzlyakova, Elena
Heitjans, Paul
Gesing, Thorsten M.
author_facet Robben, Lars
Merzlyakova, Elena
Heitjans, Paul
Gesing, Thorsten M.
author_sort Robben, Lars
collection PubMed
description Single-crystal structure refinements on lithium lanthanum zirconate (LLZO; Li(7)La(3)Zr(2)O(12)) substituted with gallium were successfully carried out in the cubic symmetry space group I [Image: see text]3d. Gallium was found on two lithium sites as well as on the lanthanum position. Due to the structural distortion of the resulting Li(6.43(2))Ga(0.52(3))La(2.67(4))Zr(2)O(12) (Ga–LLZO) single crystals, a reduction of the LLZO cubic garnet symmetry from Ia[Image: see text] d to I [Image: see text]3d was necessary, which could hardly be analysed from X-ray powder diffraction data.
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spelling pubmed-47788072016-03-22 Symmetry reduction due to gallium substitution in the garnet Li(6.43(2))Ga(0.52(3))La(2.67(4))Zr(2)O(12) Robben, Lars Merzlyakova, Elena Heitjans, Paul Gesing, Thorsten M. Acta Crystallogr E Crystallogr Commun Research Communications Single-crystal structure refinements on lithium lanthanum zirconate (LLZO; Li(7)La(3)Zr(2)O(12)) substituted with gallium were successfully carried out in the cubic symmetry space group I [Image: see text]3d. Gallium was found on two lithium sites as well as on the lanthanum position. Due to the structural distortion of the resulting Li(6.43(2))Ga(0.52(3))La(2.67(4))Zr(2)O(12) (Ga–LLZO) single crystals, a reduction of the LLZO cubic garnet symmetry from Ia[Image: see text] d to I [Image: see text]3d was necessary, which could hardly be analysed from X-ray powder diffraction data. International Union of Crystallography 2016-02-06 /pmc/articles/PMC4778807/ /pubmed/27006788 http://dx.doi.org/10.1107/S2056989016001924 Text en © Robben et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Robben, Lars
Merzlyakova, Elena
Heitjans, Paul
Gesing, Thorsten M.
Symmetry reduction due to gallium substitution in the garnet Li(6.43(2))Ga(0.52(3))La(2.67(4))Zr(2)O(12)
title Symmetry reduction due to gallium substitution in the garnet Li(6.43(2))Ga(0.52(3))La(2.67(4))Zr(2)O(12)
title_full Symmetry reduction due to gallium substitution in the garnet Li(6.43(2))Ga(0.52(3))La(2.67(4))Zr(2)O(12)
title_fullStr Symmetry reduction due to gallium substitution in the garnet Li(6.43(2))Ga(0.52(3))La(2.67(4))Zr(2)O(12)
title_full_unstemmed Symmetry reduction due to gallium substitution in the garnet Li(6.43(2))Ga(0.52(3))La(2.67(4))Zr(2)O(12)
title_short Symmetry reduction due to gallium substitution in the garnet Li(6.43(2))Ga(0.52(3))La(2.67(4))Zr(2)O(12)
title_sort symmetry reduction due to gallium substitution in the garnet li(6.43(2))ga(0.52(3))la(2.67(4))zr(2)o(12)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778807/
https://www.ncbi.nlm.nih.gov/pubmed/27006788
http://dx.doi.org/10.1107/S2056989016001924
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